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Anionic Diels–Alder Chemistry of Cyclic Sodium Dien-1-olates Delivering Highly Stereoselective and Functionalized Polycyclic Adducts

[Image: see text] Anionic Diels–Alder chemistry of electron-deficient cross-conjugated vinylogous alkenones, providing highly stable sodium dienolate ion pairs as electron-rich dienes in the presence of a weak sodium base in THF, has been newly developed, leading to a single Diels–Alder adduct, in r...

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Detalles Bibliográficos
Autores principales:	Huang, Jing-Kai, Shia, Kak-Shan
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2021
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8397436/ https://www.ncbi.nlm.nih.gov/pubmed/34289688 http://dx.doi.org/10.1021/acs.orglett.1c01807

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