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Surface Modification of Cellulose Nanocrystals with Lactone Monomers via Plasma-Induced Polymerization and Their Application in ABS Nanocomposites

The growing concern for environmental problems has motivated the use of materials obtained from bio-based resources such as cellulose nanocrystals which have a promising application acting as fillers or reinforcements of polymeric materials. In this context, in this article, plasma-induced polymeriz...

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Detalles Bibliográficos
Autores principales: Díaz de León, Ramón, Guzmán, Ediberto, López González, Ricardo, Díaz Elizondo, Alejandro, Magaña, Ilse, Neira, Guadalupe, Castañeda Facio, Adali, Valencia, Luis
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8398306/
https://www.ncbi.nlm.nih.gov/pubmed/34451239
http://dx.doi.org/10.3390/polym13162699
Descripción
Sumario:The growing concern for environmental problems has motivated the use of materials obtained from bio-based resources such as cellulose nanocrystals which have a promising application acting as fillers or reinforcements of polymeric materials. In this context, in this article, plasma-induced polymerization is proposed as a strategy to modify nanocrystals at different plasma power intensities using ε-caprolactone and δ-decalactone to improve their compatibility with polymeric matrices. The characterization was carried out using techniques such as FTIR, TGA, XRD, XPS, and AFM, with which a successful functionalization was demonstrated without altering the inherent properties of the nanocrystals. The preparation of ABS nanocomposites was carried out with the modified nanoparticles and the evaluation of the mechanical properties indicates an increase in Young’s modulus and yield stress under certain concentrations of modified cellulose nanocrystals.