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Halogens in Acetophenones Direct the Hydrogen Bond Docking Preference of Phenol via Stacking Interactions
Phenol is added to acetophenone (methyl phenyl ketone) and to six of its halogenated derivatives in a supersonic jet expansion to determine the hydrogen bonding preference of the cold and isolated 1:1 complexes by linear infrared spectroscopy. Halogenation is found to have a pronounced effect on the...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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MDPI
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8400467/ https://www.ncbi.nlm.nih.gov/pubmed/34443471 http://dx.doi.org/10.3390/molecules26164883 |