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Electrooxidation Is a Promising Approach to Functionalization of Pyrazole-Type Compounds

The review summarizes for the first time the poorly studied electrooxidative functionalization of pyrazole derivatives leading to the C–Cl, C–Br, C–I, C–S and N–N coupling products with applied properties. The introduction discusses some aspects of aromatic hydrogen substitution. Further, we mainly...

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Detalles Bibliográficos
Autores principales: Lyalin, Boris V., Sigacheva, Vera L., Kudinova, Anastasia S., Neverov, Sergey V., Kokorekin, Vladimir A., Petrosyan, Vladimir A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8400477/
https://www.ncbi.nlm.nih.gov/pubmed/34443338
http://dx.doi.org/10.3390/molecules26164749
Descripción
Sumario:The review summarizes for the first time the poorly studied electrooxidative functionalization of pyrazole derivatives leading to the C–Cl, C–Br, C–I, C–S and N–N coupling products with applied properties. The introduction discusses some aspects of aromatic hydrogen substitution. Further, we mainly consider our works on effective synthesis of the corresponding halogeno, thiocyanato and azo compounds using cheap, affordable and environmentally promising electric currents.