Oxidative N-Formylation of Secondary Amines Catalyzed by Reusable Bimetallic AuPd–Fe(3)O(4) Nanoparticles

Bimetallic catalysts are gaining attention due to their characteristics of promoting reactivity and selectivity in catalyzed reactions. Herein, a new catalytic N-formylation of secondary amines using AuPd–Fe(3)O(4) at room temperature is reported. Methanol was utilized as the formyl source and 1.0 a...

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Detalles Bibliográficos
Autores principales: Yang, Sabyuk, Cho, Ahra, Cho, Jin Hee, Kim, Byeong Moon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8400704/
https://www.ncbi.nlm.nih.gov/pubmed/34443931
http://dx.doi.org/10.3390/nano11082101
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author Yang, Sabyuk
Cho, Ahra
Cho, Jin Hee
Kim, Byeong Moon
author_facet Yang, Sabyuk
Cho, Ahra
Cho, Jin Hee
Kim, Byeong Moon
author_sort Yang, Sabyuk
collection PubMed
description Bimetallic catalysts are gaining attention due to their characteristics of promoting reactivity and selectivity in catalyzed reactions. Herein, a new catalytic N-formylation of secondary amines using AuPd–Fe(3)O(4) at room temperature is reported. Methanol was utilized as the formyl source and 1.0 atm of O(2) gas served as an external oxidant. The bimetallic catalyst, consisting of Au and Pd, makes the reaction more efficient than that using each metal separately. In addition, the catalyst can be effectively recycled owing to the Fe(3)O(4) support.
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spelling pubmed-84007042021-08-29 Oxidative N-Formylation of Secondary Amines Catalyzed by Reusable Bimetallic AuPd–Fe(3)O(4) Nanoparticles Yang, Sabyuk Cho, Ahra Cho, Jin Hee Kim, Byeong Moon Nanomaterials (Basel) Article Bimetallic catalysts are gaining attention due to their characteristics of promoting reactivity and selectivity in catalyzed reactions. Herein, a new catalytic N-formylation of secondary amines using AuPd–Fe(3)O(4) at room temperature is reported. Methanol was utilized as the formyl source and 1.0 atm of O(2) gas served as an external oxidant. The bimetallic catalyst, consisting of Au and Pd, makes the reaction more efficient than that using each metal separately. In addition, the catalyst can be effectively recycled owing to the Fe(3)O(4) support. MDPI 2021-08-18 /pmc/articles/PMC8400704/ /pubmed/34443931 http://dx.doi.org/10.3390/nano11082101 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Yang, Sabyuk
Cho, Ahra
Cho, Jin Hee
Kim, Byeong Moon
Oxidative N-Formylation of Secondary Amines Catalyzed by Reusable Bimetallic AuPd–Fe(3)O(4) Nanoparticles
title Oxidative N-Formylation of Secondary Amines Catalyzed by Reusable Bimetallic AuPd–Fe(3)O(4) Nanoparticles
title_full Oxidative N-Formylation of Secondary Amines Catalyzed by Reusable Bimetallic AuPd–Fe(3)O(4) Nanoparticles
title_fullStr Oxidative N-Formylation of Secondary Amines Catalyzed by Reusable Bimetallic AuPd–Fe(3)O(4) Nanoparticles
title_full_unstemmed Oxidative N-Formylation of Secondary Amines Catalyzed by Reusable Bimetallic AuPd–Fe(3)O(4) Nanoparticles
title_short Oxidative N-Formylation of Secondary Amines Catalyzed by Reusable Bimetallic AuPd–Fe(3)O(4) Nanoparticles
title_sort oxidative n-formylation of secondary amines catalyzed by reusable bimetallic aupd–fe(3)o(4) nanoparticles
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8400704/
https://www.ncbi.nlm.nih.gov/pubmed/34443931
http://dx.doi.org/10.3390/nano11082101
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AT chojinhee oxidativenformylationofsecondaryaminescatalyzedbyreusablebimetallicaupdfe3o4nanoparticles
AT kimbyeongmoon oxidativenformylationofsecondaryaminescatalyzedbyreusablebimetallicaupdfe3o4nanoparticles

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