NOx Storage on BaTi(0.8)Cu(0.2)O(3) Perovskite Catalysts: Addressing a Feasible Mechanism

The NOx storage mechanism on BaTi(0.8)Cu(0.2)O(3) catalyst were studied using different techniques. The results obtained by XRD, ATR, TGA and XPS under NOx storage–regeneration conditions revealed that BaO generated on the catalyst by decomposition of Ba(2)TiO(4) plays a key role in the NOx storage process. In situ DRIFTS experiments under NO/O(2) and NO/N(2) show that nitrites and nitrates are formed on the perovskite during the NOx storage process. Thus, it seems that, as for model NSR catalysts, the NOx storage on BaTi(0.8)Cu(0.2)O(3) catalyst takes place by both “nitrite” and “nitrate” routes, with the main pathway being highly dependent on the temperature and the time on stream: (i) at T < 350 °C, NO adsorption leads to nitrites formation on the catalyst and (ii) at T > 350 °C, the catalyst activity for NO oxidation promotes NO(2) generation and the nitrate formation.