Facile generation of bridged medium-sized polycyclic systems by rhodium-catalysed intramolecular (3+2) dipolar cycloadditions

Bridged medium-sized bicyclo[m.n.2] ring systems are common in natural products and potent pharmaceuticals, and pose a great synthetic challenge. Chemistry for making bicyclo[m.n.2] ring systems remains underdeveloped. Currently, there are no general reactions available for the single-step synthesis...

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Detalles Bibliográficos
Autores principales: Hou, Bao-Long, Wong, Jonathan J., Lv, Na, Wang, Yong-Qiang, Houk, K. N., Li, Chuang-Chuang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8413281/
https://www.ncbi.nlm.nih.gov/pubmed/34475378
http://dx.doi.org/10.1038/s41467-021-25513-7

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8413281/
https://www.ncbi.nlm.nih.gov/pubmed/34475378
http://dx.doi.org/10.1038/s41467-021-25513-7

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