Access to 2,6-Dipropargylated BODIPYs as “Clickable” Congeners of Pyrromethene-567 Dye: Photostability and Synthetic Versatility

[Image: see text] Hitherto unreported 2,6-dipropargyl-1,3,5,7-tetramethyl BODIPYs can be efficiently prepared by a Nicholas reaction/decomplexation protocol from 1,3,5,7-tetramethyl BODIPYs. The title compounds, which improve the BODIPY photostability by retaining their inherent photophysical and ph...

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Autores principales: Uriel, Clara, Gómez, Ana M., García Martínez de la Hidalga, Enrique, Bañuelos, Jorge, Garcia-Moreno, Inmaculada, López, J. Cristobal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8419863/
https://www.ncbi.nlm.nih.gov/pubmed/34403255
http://dx.doi.org/10.1021/acs.orglett.1c02380
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author Uriel, Clara
Gómez, Ana M.
García Martínez de la Hidalga, Enrique
Bañuelos, Jorge
Garcia-Moreno, Inmaculada
López, J. Cristobal
author_facet Uriel, Clara
Gómez, Ana M.
García Martínez de la Hidalga, Enrique
Bañuelos, Jorge
Garcia-Moreno, Inmaculada
López, J. Cristobal
author_sort Uriel, Clara
collection PubMed
description [Image: see text] Hitherto unreported 2,6-dipropargyl-1,3,5,7-tetramethyl BODIPYs can be efficiently prepared by a Nicholas reaction/decomplexation protocol from 1,3,5,7-tetramethyl BODIPYs. The title compounds, which improve the BODIPY photostability by retaining their inherent photophysical and photochemical properties, can be engaged in efficient copper(I)-catalyzed azide–alkyne cycloaddition (CuAAC) “click-type” reactions with azido derivatives to provide all-BODIPY-triads or conjugated BODIPYs.
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spelling pubmed-84198632021-09-07 Access to 2,6-Dipropargylated BODIPYs as “Clickable” Congeners of Pyrromethene-567 Dye: Photostability and Synthetic Versatility Uriel, Clara Gómez, Ana M. García Martínez de la Hidalga, Enrique Bañuelos, Jorge Garcia-Moreno, Inmaculada López, J. Cristobal Org Lett [Image: see text] Hitherto unreported 2,6-dipropargyl-1,3,5,7-tetramethyl BODIPYs can be efficiently prepared by a Nicholas reaction/decomplexation protocol from 1,3,5,7-tetramethyl BODIPYs. The title compounds, which improve the BODIPY photostability by retaining their inherent photophysical and photochemical properties, can be engaged in efficient copper(I)-catalyzed azide–alkyne cycloaddition (CuAAC) “click-type” reactions with azido derivatives to provide all-BODIPY-triads or conjugated BODIPYs. American Chemical Society 2021-08-17 2021-09-03 /pmc/articles/PMC8419863/ /pubmed/34403255 http://dx.doi.org/10.1021/acs.orglett.1c02380 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Uriel, Clara
Gómez, Ana M.
García Martínez de la Hidalga, Enrique
Bañuelos, Jorge
Garcia-Moreno, Inmaculada
López, J. Cristobal
Access to 2,6-Dipropargylated BODIPYs as “Clickable” Congeners of Pyrromethene-567 Dye: Photostability and Synthetic Versatility
title Access to 2,6-Dipropargylated BODIPYs as “Clickable” Congeners of Pyrromethene-567 Dye: Photostability and Synthetic Versatility
title_full Access to 2,6-Dipropargylated BODIPYs as “Clickable” Congeners of Pyrromethene-567 Dye: Photostability and Synthetic Versatility
title_fullStr Access to 2,6-Dipropargylated BODIPYs as “Clickable” Congeners of Pyrromethene-567 Dye: Photostability and Synthetic Versatility
title_full_unstemmed Access to 2,6-Dipropargylated BODIPYs as “Clickable” Congeners of Pyrromethene-567 Dye: Photostability and Synthetic Versatility
title_short Access to 2,6-Dipropargylated BODIPYs as “Clickable” Congeners of Pyrromethene-567 Dye: Photostability and Synthetic Versatility
title_sort access to 2,6-dipropargylated bodipys as “clickable” congeners of pyrromethene-567 dye: photostability and synthetic versatility
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8419863/
https://www.ncbi.nlm.nih.gov/pubmed/34403255
http://dx.doi.org/10.1021/acs.orglett.1c02380
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