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Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-dichloro-1-(4-methylphenyl)ethenyl]-2-(4-methoxyphenyl)diazene
The asymmetric unit of the title compound, C(16)H(14)Cl(2)N(2)O, comprises two similar molecules, A and B, in which the dihedral angles between the two aromatic rings are 70.1 (3) and 73.2 (2)°, respectively. The crystal structure features short C—H⋯Cl and C—H⋯O contacts and C—H⋯π and van der Waals...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8423004/ https://www.ncbi.nlm.nih.gov/pubmed/34584771 http://dx.doi.org/10.1107/S2056989021008756 |
Sumario: | The asymmetric unit of the title compound, C(16)H(14)Cl(2)N(2)O, comprises two similar molecules, A and B, in which the dihedral angles between the two aromatic rings are 70.1 (3) and 73.2 (2)°, respectively. The crystal structure features short C—H⋯Cl and C—H⋯O contacts and C—H⋯π and van der Waals interactions. The title compound was refined as a two-component non-merohedral twin, BASF 0.1076 (5). The Hirshfeld surface analysis and two-dimensional fingerprint plots show that H⋯H (38.2% for molecule A; 36.0% for molecule B), Cl⋯H/H⋯Cl (24.6% for molecule A; 26.7% for molecule B) and C⋯H/H⋯C (20.0% for molecule A; 20.2% for molecule B) interactions are the most important contributors to the crystal packing. |
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