Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-di­chloro-1-(4-methyl­phen­yl)ethen­yl]-2-(4-meth­oxy­phen­yl)diazene

The asymmetric unit of the title compound, C(16)H(14)Cl(2)N(2)O, comprises two similar mol­ecules, A and B, in which the dihedral angles between the two aromatic rings are 70.1 (3) and 73.2 (2)°, respectively. The crystal structure features short C—H⋯Cl and C—H⋯O contacts and C—H⋯π and van der Waals...

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Autores principales: Shikhaliyev, Namiq Q., Atioğlu, Zeliha, Akkurt, Mehmet, Qacar, Ayten M., Askerov, Rizvan K., Bhattarai, Ajaya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8423004/
https://www.ncbi.nlm.nih.gov/pubmed/34584771
http://dx.doi.org/10.1107/S2056989021008756
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author Shikhaliyev, Namiq Q.
Atioğlu, Zeliha
Akkurt, Mehmet
Qacar, Ayten M.
Askerov, Rizvan K.
Bhattarai, Ajaya
author_facet Shikhaliyev, Namiq Q.
Atioğlu, Zeliha
Akkurt, Mehmet
Qacar, Ayten M.
Askerov, Rizvan K.
Bhattarai, Ajaya
author_sort Shikhaliyev, Namiq Q.
collection PubMed
description The asymmetric unit of the title compound, C(16)H(14)Cl(2)N(2)O, comprises two similar mol­ecules, A and B, in which the dihedral angles between the two aromatic rings are 70.1 (3) and 73.2 (2)°, respectively. The crystal structure features short C—H⋯Cl and C—H⋯O contacts and C—H⋯π and van der Waals inter­actions. The title compound was refined as a two-component non-merohedral twin, BASF 0.1076 (5). The Hirshfeld surface analysis and two-dimensional fingerprint plots show that H⋯H (38.2% for mol­ecule A; 36.0% for mol­ecule B), Cl⋯H/H⋯Cl (24.6% for mol­ecule A; 26.7% for mol­ecule B) and C⋯H/H⋯C (20.0% for mol­ecule A; 20.2% for mol­ecule B) inter­actions are the most important contributors to the crystal packing.
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spelling pubmed-84230042021-09-27 Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-di­chloro-1-(4-methyl­phen­yl)ethen­yl]-2-(4-meth­oxy­phen­yl)diazene Shikhaliyev, Namiq Q. Atioğlu, Zeliha Akkurt, Mehmet Qacar, Ayten M. Askerov, Rizvan K. Bhattarai, Ajaya Acta Crystallogr E Crystallogr Commun Research Communications The asymmetric unit of the title compound, C(16)H(14)Cl(2)N(2)O, comprises two similar mol­ecules, A and B, in which the dihedral angles between the two aromatic rings are 70.1 (3) and 73.2 (2)°, respectively. The crystal structure features short C—H⋯Cl and C—H⋯O contacts and C—H⋯π and van der Waals inter­actions. The title compound was refined as a two-component non-merohedral twin, BASF 0.1076 (5). The Hirshfeld surface analysis and two-dimensional fingerprint plots show that H⋯H (38.2% for mol­ecule A; 36.0% for mol­ecule B), Cl⋯H/H⋯Cl (24.6% for mol­ecule A; 26.7% for mol­ecule B) and C⋯H/H⋯C (20.0% for mol­ecule A; 20.2% for mol­ecule B) inter­actions are the most important contributors to the crystal packing. International Union of Crystallography 2021-08-27 /pmc/articles/PMC8423004/ /pubmed/34584771 http://dx.doi.org/10.1107/S2056989021008756 Text en © Shikhaliyev et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Shikhaliyev, Namiq Q.
Atioğlu, Zeliha
Akkurt, Mehmet
Qacar, Ayten M.
Askerov, Rizvan K.
Bhattarai, Ajaya
Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-di­chloro-1-(4-methyl­phen­yl)ethen­yl]-2-(4-meth­oxy­phen­yl)diazene
title Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-di­chloro-1-(4-methyl­phen­yl)ethen­yl]-2-(4-meth­oxy­phen­yl)diazene
title_full Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-di­chloro-1-(4-methyl­phen­yl)ethen­yl]-2-(4-meth­oxy­phen­yl)diazene
title_fullStr Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-di­chloro-1-(4-methyl­phen­yl)ethen­yl]-2-(4-meth­oxy­phen­yl)diazene
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-di­chloro-1-(4-methyl­phen­yl)ethen­yl]-2-(4-meth­oxy­phen­yl)diazene
title_short Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-di­chloro-1-(4-methyl­phen­yl)ethen­yl]-2-(4-meth­oxy­phen­yl)diazene
title_sort crystal structure and hirshfeld surface analysis of (e)-1-[2,2-di­chloro-1-(4-methyl­phen­yl)ethen­yl]-2-(4-meth­oxy­phen­yl)diazene
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8423004/
https://www.ncbi.nlm.nih.gov/pubmed/34584771
http://dx.doi.org/10.1107/S2056989021008756
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