LiNa(3)(SO(4))(2)·6H(2)O: a lithium double salt causing trouble in the industrial conversion of Li(2)SO(4) into LiOH

Lithium tris­odium bis­(sulfate) hexa­hydrate, LiNa(3)(SO(4))(2)·6H(2)O was crystallized from aqueous solution at 298 K and the structure solved at different temperatures between 90 and 293 K. The structure is isomorphic with the corresponding molybdate and selenate double salt hydrate. It belongs t...

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Detalles Bibliográficos
Autores principales: Schmidt, Horst, Paschke, Iris, Voigt, Wolfgang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8423005/
https://www.ncbi.nlm.nih.gov/pubmed/34584763
http://dx.doi.org/10.1107/S2056989021008057
Descripción
Sumario:Lithium tris­odium bis­(sulfate) hexa­hydrate, LiNa(3)(SO(4))(2)·6H(2)O was crystallized from aqueous solution at 298 K and the structure solved at different temperatures between 90 and 293 K. The structure is isomorphic with the corresponding molybdate and selenate double salt hydrate. It belongs to the non-centrosymmetric trigonal space group R3c (161). The temperature dependence of the lattice parameters has been determined. Further characterization by powder XRD and thermal analysis is reported.

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