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Crystal structure and Hirshfeld surface analysis of (3Z)-7-methoxy-3-(2-phenylhydrazinylidene)-1-benzofuran-2(3H)-one
In the title compound, C(15)H(12)N(2)O(3), pairs of molecules are linked into dimers by N—H⋯O hydrogen bonds, forming an R (2) (2)(12) ring motif, with the dimers stacked along the a axis. These dimers are connected through π–π stacking interactions between the centroids of the benzene and furan r...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8423015/ https://www.ncbi.nlm.nih.gov/pubmed/34584760 http://dx.doi.org/10.1107/S2056989021007891 |
Sumario: | In the title compound, C(15)H(12)N(2)O(3), pairs of molecules are linked into dimers by N—H⋯O hydrogen bonds, forming an R (2) (2)(12) ring motif, with the dimers stacked along the a axis. These dimers are connected through π–π stacking interactions between the centroids of the benzene and furan rings of their 2,3-dihydro-1-benzofuran ring systems. Furthermore, there exists a C—H⋯π interaction that consolidates the crystal packing. A Hirshfeld surface analysis indicates that the most important contacts are H⋯H (40.7%), O⋯H/H⋯O (24.7%), C⋯H/H⋯C (16.1%) and C⋯C (8.8%). |
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