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Crystal structure and Hirshfeld surface analysis of (3Z)-7-meth­oxy-3-(2-phenyl­hydrazinyl­idene)-1-benzo­furan-2(3H)-one

In the title compound, C(15)H(12)N(2)O(3), pairs of mol­ecules are linked into dimers by N—H⋯O hydrogen bonds, forming an R (2) (2)(12) ring motif, with the dimers stacked along the a axis. These dimers are connected through π–π stacking inter­actions between the centroids of the benzene and furan r...

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Detalles Bibliográficos
Autores principales: Atioğlu, Zeliha, Akkurt, Mehmet, Askerova, Ulviyya F., Mukhtarova, Sevinc H., Askerov, Rizvan K., Mlowe, Sixberth
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8423015/
https://www.ncbi.nlm.nih.gov/pubmed/34584760
http://dx.doi.org/10.1107/S2056989021007891
Descripción
Sumario:In the title compound, C(15)H(12)N(2)O(3), pairs of mol­ecules are linked into dimers by N—H⋯O hydrogen bonds, forming an R (2) (2)(12) ring motif, with the dimers stacked along the a axis. These dimers are connected through π–π stacking inter­actions between the centroids of the benzene and furan rings of their 2,3-di­hydro-1-benzo­furan ring systems. Furthermore, there exists a C—H⋯π inter­action that consolidates the crystal packing. A Hirshfeld surface analysis indicates that the most important contacts are H⋯H (40.7%), O⋯H/H⋯O (24.7%), C⋯H/H⋯C (16.1%) and C⋯C (8.8%).