Crystal structure and Hirshfeld surface analysis of (3Z)-7-meth­oxy-3-(2-phenyl­hydrazinyl­idene)-1-benzo­furan-2(3H)-one

In the title compound, C(15)H(12)N(2)O(3), pairs of mol­ecules are linked into dimers by N—H⋯O hydrogen bonds, forming an R (2) (2)(12) ring motif, with the dimers stacked along the a axis. These dimers are connected through π–π stacking inter­actions between the centroids of the benzene and furan r...

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Autores principales: Atioğlu, Zeliha, Akkurt, Mehmet, Askerova, Ulviyya F., Mukhtarova, Sevinc H., Askerov, Rizvan K., Mlowe, Sixberth
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8423015/
https://www.ncbi.nlm.nih.gov/pubmed/34584760
http://dx.doi.org/10.1107/S2056989021007891
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author Atioğlu, Zeliha
Akkurt, Mehmet
Askerova, Ulviyya F.
Mukhtarova, Sevinc H.
Askerov, Rizvan K.
Mlowe, Sixberth
author_facet Atioğlu, Zeliha
Akkurt, Mehmet
Askerova, Ulviyya F.
Mukhtarova, Sevinc H.
Askerov, Rizvan K.
Mlowe, Sixberth
author_sort Atioğlu, Zeliha
collection PubMed
description In the title compound, C(15)H(12)N(2)O(3), pairs of mol­ecules are linked into dimers by N—H⋯O hydrogen bonds, forming an R (2) (2)(12) ring motif, with the dimers stacked along the a axis. These dimers are connected through π–π stacking inter­actions between the centroids of the benzene and furan rings of their 2,3-di­hydro-1-benzo­furan ring systems. Furthermore, there exists a C—H⋯π inter­action that consolidates the crystal packing. A Hirshfeld surface analysis indicates that the most important contacts are H⋯H (40.7%), O⋯H/H⋯O (24.7%), C⋯H/H⋯C (16.1%) and C⋯C (8.8%).
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spelling pubmed-84230152021-09-27 Crystal structure and Hirshfeld surface analysis of (3Z)-7-meth­oxy-3-(2-phenyl­hydrazinyl­idene)-1-benzo­furan-2(3H)-one Atioğlu, Zeliha Akkurt, Mehmet Askerova, Ulviyya F. Mukhtarova, Sevinc H. Askerov, Rizvan K. Mlowe, Sixberth Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(15)H(12)N(2)O(3), pairs of mol­ecules are linked into dimers by N—H⋯O hydrogen bonds, forming an R (2) (2)(12) ring motif, with the dimers stacked along the a axis. These dimers are connected through π–π stacking inter­actions between the centroids of the benzene and furan rings of their 2,3-di­hydro-1-benzo­furan ring systems. Furthermore, there exists a C—H⋯π inter­action that consolidates the crystal packing. A Hirshfeld surface analysis indicates that the most important contacts are H⋯H (40.7%), O⋯H/H⋯O (24.7%), C⋯H/H⋯C (16.1%) and C⋯C (8.8%). International Union of Crystallography 2021-08-06 /pmc/articles/PMC8423015/ /pubmed/34584760 http://dx.doi.org/10.1107/S2056989021007891 Text en © Atioğlu et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Atioğlu, Zeliha
Akkurt, Mehmet
Askerova, Ulviyya F.
Mukhtarova, Sevinc H.
Askerov, Rizvan K.
Mlowe, Sixberth
Crystal structure and Hirshfeld surface analysis of (3Z)-7-meth­oxy-3-(2-phenyl­hydrazinyl­idene)-1-benzo­furan-2(3H)-one
title Crystal structure and Hirshfeld surface analysis of (3Z)-7-meth­oxy-3-(2-phenyl­hydrazinyl­idene)-1-benzo­furan-2(3H)-one
title_full Crystal structure and Hirshfeld surface analysis of (3Z)-7-meth­oxy-3-(2-phenyl­hydrazinyl­idene)-1-benzo­furan-2(3H)-one
title_fullStr Crystal structure and Hirshfeld surface analysis of (3Z)-7-meth­oxy-3-(2-phenyl­hydrazinyl­idene)-1-benzo­furan-2(3H)-one
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of (3Z)-7-meth­oxy-3-(2-phenyl­hydrazinyl­idene)-1-benzo­furan-2(3H)-one
title_short Crystal structure and Hirshfeld surface analysis of (3Z)-7-meth­oxy-3-(2-phenyl­hydrazinyl­idene)-1-benzo­furan-2(3H)-one
title_sort crystal structure and hirshfeld surface analysis of (3z)-7-meth­oxy-3-(2-phenyl­hydrazinyl­idene)-1-benzo­furan-2(3h)-one
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8423015/
https://www.ncbi.nlm.nih.gov/pubmed/34584760
http://dx.doi.org/10.1107/S2056989021007891
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