Open-Ended Metallodithiolene Complexes with the 1,2,4,5-Tetrakis(diphenylphosphino)benzene Ligand: Modular Building Elements for the Synthesis of Multimetal Complexes

[Image: see text] Open-ended, singly metalated dithiolene complexes with 1,2,4,5-tetrakis(diphenylphosphino)benzene (tpbz) are prepared either by ligand transfer to [Cl(2)M(tpbz)] from (R(2)C(2)S(2))SnR′(2) (R = CN, R′ = Me; R = Me, R′ = (n)Bu) or by a direct reaction between tpbz and [M(S(2)C(2)R(2...

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Autores principales: Kumar, Satyendra, Selvachandran, Malathy, Arumugam, Kuppuswamy, Shaw, Mohamed C., Wu, Che, Maurer, Michael, Zhang, Xiaodong, Sproules, Stephen, Mague, Joel T., Donahue, James P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8424627/
https://www.ncbi.nlm.nih.gov/pubmed/34370468
http://dx.doi.org/10.1021/acs.inorgchem.1c01573

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