Holmium(III) Single-Ion Magnet for Cryomagnetic Refrigeration Based on an MRI Contrast Agent Derivative

[Image: see text] The coexistence of field-induced blockage of the magnetization and significant magnetocaloric effects in the low-temperature region occurs in a mononuclear holmium(III) diethylenetriamine-N,N,N′,N″,N″-pentaacetate complex, whose gadolinium(III) analogue is a commercial MRI contrast...

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Autores principales: Rodríguez-Barea, Borja, Mayans, Júlia, Rabelo, Renato, Sanchis-Perucho, Adrián, Moliner, Nicolás, Martínez-Lillo, José, Julve, Miguel, Lloret, Francesc, Ruiz-García, Rafael, Cano, Joan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8424628/
https://www.ncbi.nlm.nih.gov/pubmed/34424680
http://dx.doi.org/10.1021/acs.inorgchem.1c01905
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author Rodríguez-Barea, Borja
Mayans, Júlia
Rabelo, Renato
Sanchis-Perucho, Adrián
Moliner, Nicolás
Martínez-Lillo, José
Julve, Miguel
Lloret, Francesc
Ruiz-García, Rafael
Cano, Joan
author_facet Rodríguez-Barea, Borja
Mayans, Júlia
Rabelo, Renato
Sanchis-Perucho, Adrián
Moliner, Nicolás
Martínez-Lillo, José
Julve, Miguel
Lloret, Francesc
Ruiz-García, Rafael
Cano, Joan
author_sort Rodríguez-Barea, Borja
collection PubMed
description [Image: see text] The coexistence of field-induced blockage of the magnetization and significant magnetocaloric effects in the low-temperature region occurs in a mononuclear holmium(III) diethylenetriamine-N,N,N′,N″,N″-pentaacetate complex, whose gadolinium(III) analogue is a commercial MRI contrast agent. Both properties make it a suitable candidate for cryogenic magnetic refrigeration, thus enlarging the variety of applications of this simple class of multifunctional molecular nanomagnets.
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spelling pubmed-84246282021-09-08 Holmium(III) Single-Ion Magnet for Cryomagnetic Refrigeration Based on an MRI Contrast Agent Derivative Rodríguez-Barea, Borja Mayans, Júlia Rabelo, Renato Sanchis-Perucho, Adrián Moliner, Nicolás Martínez-Lillo, José Julve, Miguel Lloret, Francesc Ruiz-García, Rafael Cano, Joan Inorg Chem [Image: see text] The coexistence of field-induced blockage of the magnetization and significant magnetocaloric effects in the low-temperature region occurs in a mononuclear holmium(III) diethylenetriamine-N,N,N′,N″,N″-pentaacetate complex, whose gadolinium(III) analogue is a commercial MRI contrast agent. Both properties make it a suitable candidate for cryogenic magnetic refrigeration, thus enlarging the variety of applications of this simple class of multifunctional molecular nanomagnets. American Chemical Society 2021-08-23 2021-09-06 /pmc/articles/PMC8424628/ /pubmed/34424680 http://dx.doi.org/10.1021/acs.inorgchem.1c01905 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Rodríguez-Barea, Borja
Mayans, Júlia
Rabelo, Renato
Sanchis-Perucho, Adrián
Moliner, Nicolás
Martínez-Lillo, José
Julve, Miguel
Lloret, Francesc
Ruiz-García, Rafael
Cano, Joan
Holmium(III) Single-Ion Magnet for Cryomagnetic Refrigeration Based on an MRI Contrast Agent Derivative
title Holmium(III) Single-Ion Magnet for Cryomagnetic Refrigeration Based on an MRI Contrast Agent Derivative
title_full Holmium(III) Single-Ion Magnet for Cryomagnetic Refrigeration Based on an MRI Contrast Agent Derivative
title_fullStr Holmium(III) Single-Ion Magnet for Cryomagnetic Refrigeration Based on an MRI Contrast Agent Derivative
title_full_unstemmed Holmium(III) Single-Ion Magnet for Cryomagnetic Refrigeration Based on an MRI Contrast Agent Derivative
title_short Holmium(III) Single-Ion Magnet for Cryomagnetic Refrigeration Based on an MRI Contrast Agent Derivative
title_sort holmium(iii) single-ion magnet for cryomagnetic refrigeration based on an mri contrast agent derivative
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8424628/
https://www.ncbi.nlm.nih.gov/pubmed/34424680
http://dx.doi.org/10.1021/acs.inorgchem.1c01905
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