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The Phospha-Bora-Wittig Reaction

[Image: see text] We report the phospha-bora-Wittig reaction for the direct preparation of phosphaalkenes from aldehydes, ketones, esters, or amides. The transient phosphaborene Mes*P=B–NR(2) reacts with carbonyl compounds to form 1,2,3-phosphaboraoxetanes, analogues of oxaphosphetane intermediates...

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Detalles Bibliográficos
Autores principales:	Borys, Andryj M., Rice, Ella F., Nichol, Gary S., Cowley, Michael J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2021
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8431359/ https://www.ncbi.nlm.nih.gov/pubmed/34437805 http://dx.doi.org/10.1021/jacs.1c06228

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