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Plasticized Poly(vinyl chloride) Modified with Developed Fire Retardant System Based on Nanoclay and L-histidinium Dihydrogen Phosphate-Phosphoric Acid

The current work assessed the burning behavior of plasticized poly(vinyl chloride) (PVC-P) modified with a two-component composition, consisting of L-histidinium dihydrogen phosphate-phosphoric acid (LHP) and nanoclay (n). The thermal and thermodynamical properties of the PVC-P containing from 10 to...

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Detalles Bibliográficos
Autores principales: Sałasińska, Kamila, Barczewski, Mateusz, Celiński, Maciej, Kozikowski, Paweł, Kozera, Rafał, Sodo, Aleksandra, Mirowski, Jacek, Zajchowski, Stanisław, Tomaszewska, Jolanta
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8433658/
https://www.ncbi.nlm.nih.gov/pubmed/34502949
http://dx.doi.org/10.3390/polym13172909
Descripción
Sumario:The current work assessed the burning behavior of plasticized poly(vinyl chloride) (PVC-P) modified with a two-component composition, consisting of L-histidinium dihydrogen phosphate-phosphoric acid (LHP) and nanoclay (n). The thermal and thermodynamical properties of the PVC-P containing from 10 to 30 wt% of the fire retardant system (FRS) were determined by thermogravimetric analysis (TG) as well as by dynamic mechanical thermal analysis (DMTA). In contrast, fire behavior and smoke emission were studied with a cone calorimeter (CC) and smoke density chamber. The research was complemented by a microstructure analysis, using a scanning electron microscope, of the materials before and after burning CC tests. The effects were compared to those achieved for PVC-P, PVC-P with a commercially available fire retardant, the substrate used for the produced LHP, and the mixture of LHP and zinc borate, both of which contained the same share of nanoclay. Based on a notable improvement, especially in smoke suppression suggests that the n/LHP system may be a candidate fire retardant for decreasing the flammability of PVC-P.