Cargando…

Microwave-Assisted Ionic Liquid-Catalyzed Selective Monoesterification of Alkylphosphonic Acids—An Experimental and a Theoretical Study

It is well-known that the P-acids including phosphonic acids resist undergoing direct esterification. However, it was found that a series of alkylphoshonic acids could be involved in monoesterification with C(2)–C(4) alcohols under microwave (MW) irradiation in the presence of [bmim][BF(4)] as an ad...

Descripción completa

Detalles Bibliográficos
Autores principales:	Harsági, Nikoletta, Henyecz, Réka, Ábrányi-Balogh, Péter, Drahos, László, Keglevich, György
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2021
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8434145/ https://www.ncbi.nlm.nih.gov/pubmed/34500735 http://dx.doi.org/10.3390/molecules26175303

Ejemplares similares

A Study on the Direct Esterification of Monoalkylphosphates and Dialkylphosphates; The Conversion of the Latter Species to Trialkylphosphates by Alkylating Esterification †
por: Ábrányi-Balogh, Péter, et al.
Publicado: (2022)

The Palladium Acetate‐Catalyzed Microwave‐Assisted Hirao Reaction without an Added Phosphorus Ligand as a “Green” Protocol: A Quantum Chemical Study on the Mechanism
por: Keglevich, György, et al.
Publicado: (2017)

Experimental and Theoretical Study on the “2,2′-Bipiridyl-Ni-Catalyzed” Hirao Reaction of >P(O)H Reagents and Halobenzenes: A Ni(0) → Ni(II) or a Ni(II) → Ni(IV) Mechanism?
por: Keglevich, György, et al.
Publicado: (2020)

Focusing on the Catalysts of the Pd- and Ni-Catalyzed Hirao Reactions
por: Keglevich, György, et al.
Publicado: (2020)

Continuous Flow Esterification of a H-Phosphinic Acid, and Transesterification of H-Phosphinates and H-Phosphonates under Microwave Conditions
por: Kiss, Nóra Zsuzsa, et al.
Publicado: (2020)

The Hydrolysis of Phosphinates and Phosphonates: A Review
por: Harsági, Nikoletta, et al.
Publicado: (2021)

New Developments on the Hirao Reactions, Especially from “Green” Point of View
por: Henyecz, Réka, et al.
Publicado: (2019)

The synthesis of α-aryl-α-aminophosphonates and α-aryl-α-aminophosphine oxides by the microwave-assisted Pudovik reaction
por: Bálint, Erika, et al.
Publicado: (2017)

Optimization and a Kinetic Study on the Acidic Hydrolysis of Dialkyl α-Hydroxybenzylphosphonates
por: Harsági, Nikoletta, et al.
Publicado: (2020)

A Mechanistic Study on the Formation of Dronic Acids
por: Ábrányi-Balogh, Péter, et al.
Publicado: (2021)

A Mechanistic Study on the Tautomerism of H-Phosphonates, H-Phosphinates and Secondary Phosphine Oxides
por: Vincze, Daniella, et al.
Publicado: (2019)

Origin of alkylphosphonic acids in the interstellar medium
por: Turner, Andrew M., et al.
Publicado: (2019)

Pd-Catalyzed microwave-assisted synthesis of phosphonated 13α-estrones as potential OATP2B1, 17β-HSD1 and/or STS inhibitors
por: Jójárt, Rebeka, et al.
Publicado: (2018)

1-(Acylamino)alkylphosphonic Acids—Alkaline Deacylation
por: Cypryk, Marek, et al.
Publicado: (2018)

Microwave-Assisted Resolution of α-Lipoic Acid Catalyzed by an Ionic Liquid Co-Lyophilized Lipase
por: Liu, Ning, et al.
Publicado: (2015)

Microwave-Assisted Palladium Acetate-Catalyzed C–P Cross-Coupling of Arylboronic Acids and >P(O)H Reagents in the Absence of the Usual Mono- and Bidentate P-Ligands: Mechanistic Insights
por: Huszár, Bianka, et al.
Publicado: (2023)

Microwaves as “Co-Catalysts” or as Substitute for Catalysts in Organophosphorus Chemistry
por: Keglevich, György
Publicado: (2021)

Rapid and Efficient Functionalized Ionic Liquid-Catalyzed Aldol Condensation Reactions Associated with Microwave Irradiation
por: Wang, Chang, et al.
Publicado: (2014)

Synthesis and In Vitro Anticancer Evaluation of Novel Chrysin and 7-Aminochrysin Derivatives
por: Mayer, Szabolcs, et al.
Publicado: (2020)

Microwave-assisted synthesis of N,N-bis(phosphinoylmethyl)amines and N,N,N-tris(phosphinoylmethyl)amines bearing different substituents on the phosphorus atoms
por: Bálint, Erika, et al.
Publicado: (2019)

Palladium-catalyzed Sonogashira coupling reactions in γ-valerolactone-based ionic liquids
por: Orha, László, et al.
Publicado: (2019)

Activation-Free Sulfonyl Fluoride Probes for Fragment Screening
por: Petri, László, et al.
Publicado: (2023)

Microwave-Assisted Kabachnik–Fields Reaction with Amino Alcohols as the Amine Component
por: Tajti, Ádám, et al.
Publicado: (2019)

The Hydrolytic Stability and Degradation Mechanism of a Hierarchically Porous Metal Alkylphosphonate Framework
por: Lv, Kai, et al.
Publicado: (2018)

Friedel–Crafts-type reaction of pyrene with diethyl 1-(isothiocyanato)alkylphosphonates. Efficient synthesis of highly fluorescent diethyl 1-(pyrene-1-carboxamido)alkylphosphonates and 1-(pyrene-1-carboxamido)methylphosphonic acid
por: Wrona-Piotrowicz, Anna, et al.
Publicado: (2015)

Efficient Lewis Acid Ionic Liquid-Catalyzed Synthesis of the Key Intermediate of Coenzyme Q(10) under Microwave Irradiation
por: Chen, Yue, et al.
Publicado: (2010)

Synthesis of tertiary alkylphosphonate oligonucleotides through light-driven radical-polar crossover reactions
por: Ota, Kenji, et al.
Publicado: (2023)

Application of the Microwave Technique in Continuous Flow Processing of Organophosphorus Chemical Reactions
por: Bálint, Erika, et al.
Publicado: (2019)

Application of Ionic Liquids in the Microwave-Assisted Extraction of Pectin from Lemon Peels
por: Guolin, Huang, et al.
Publicado: (2012)

Microwave-Assisted Syntheses in Recyclable Ionic Liquids: Photoresists Based on Renewable Resources
por: Petit, Charlotte, et al.
Publicado: (2015)

Microwave-assisted synthesis of (aminomethylene)bisphosphine oxides and (aminomethylene)bisphosphonates by a three-component condensation
por: Bálint, Erika, et al.
Publicado: (2016)

Effect of Binding Linkers on the Efficiency and Metabolite Profile of Biomimetic Reactions Catalyzed by Immobilized Metalloporphyrin
por: Balogh, György T., et al.
Publicado: (2022)

Impact of Perfluoro and Alkylphosphonic Self-Assembled Monolayers on Tribological and Antimicrobial Properties of Ti-DLC Coatings
por: Cichomski, Michal, et al.
Publicado: (2019)

Application of Ionic Liquids in the Microwave-Assisted Extraction of Proanthocyanidins from Larix gmelini Bark
por: Yang, Lei, et al.
Publicado: (2012)

Intercalation of Ionic Liquids into LDH Structures for Microwave-Accelerated Polymerizations
por: Beneš, Hynek, et al.
Publicado: (2023)

A novel three-component reaction between isocyanides, alcohols or thiols and elemental sulfur: a mild, catalyst-free approach towards O-thiocarbamates and dithiocarbamates
por: Németh, András György, et al.
Publicado: (2019)

Ionic Liquids: Efficient Media for the Lipase-Catalyzed Michael Addition
por: Fan, Yunchang, et al.
Publicado: (2018)

A Study of the Bisphosphonic Derivatives from the Pudovik Reaction of Dialkyl α-Oxophosphonates and >P(O)H Reagents: X-ray Structure and Bioactivity
por: Szalai, Zsuzsanna, et al.
Publicado: (2023)

Microwave-assisted simple synthesis of 2-anilinopyrimidines by the reaction of 2-chloro-4,6-dimethylpyrimidine with aniline derivatives
por: Campestre, Cristina, et al.
Publicado: (2020)

Application of Boroisoquinoline Fluorophores as Chemodosimeters for Fluoride Ion and Pd (0)
por: Sóvári, Dénes, et al.
Publicado: (2020)

Cannot write session to /tmp/vufind_sessions/sess_qj57t0mech6oq9n5e09904orhd