Slow magnetic relaxation in distorted tetrahedral Dy(iii) aryloxide complexes

Three distorted tetrahedral Dy(iii) aryloxide complexes, [Na(THF)(6)][Dy(OAr(Ad(2)tBu))(2)Cl(2)] (1) (OAr(Ad(2)tBu) = OC(6)H(2)Adamantyl(2)-2,6-(t)Bu-4) and [Na(THF)(6)][Dy(OMes*)(3)X] (X = Cl, 2; BH(4), 3), (OMes* = OC(6)H(2)(t)Bu(3)-2,4,6) exhibit easy axis magnetic anisotropy and slow magnetic re...

Descripción completa

Detalles Bibliográficos
Autores principales: Parmar, Vijay S., Gransbury, Gemma K., Whitehead, George F. S., Mills, David P., Winpenny, Richard E. P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8438701/
https://www.ncbi.nlm.nih.gov/pubmed/34519290
http://dx.doi.org/10.1039/d1cc02707g
_version_ 1783752398951415808
author Parmar, Vijay S.
Gransbury, Gemma K.
Whitehead, George F. S.
Mills, David P.
Winpenny, Richard E. P.
author_facet Parmar, Vijay S.
Gransbury, Gemma K.
Whitehead, George F. S.
Mills, David P.
Winpenny, Richard E. P.
author_sort Parmar, Vijay S.
collection PubMed
description Three distorted tetrahedral Dy(iii) aryloxide complexes, [Na(THF)(6)][Dy(OAr(Ad(2)tBu))(2)Cl(2)] (1) (OAr(Ad(2)tBu) = OC(6)H(2)Adamantyl(2)-2,6-(t)Bu-4) and [Na(THF)(6)][Dy(OMes*)(3)X] (X = Cl, 2; BH(4), 3), (OMes* = OC(6)H(2)(t)Bu(3)-2,4,6) exhibit easy axis magnetic anisotropy and slow magnetic relaxation at zero field, with relaxation rates 1 < 2 < 3.
format Online
Article
Text
id pubmed-8438701
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-84387012021-09-27 Slow magnetic relaxation in distorted tetrahedral Dy(iii) aryloxide complexes Parmar, Vijay S. Gransbury, Gemma K. Whitehead, George F. S. Mills, David P. Winpenny, Richard E. P. Chem Commun (Camb) Chemistry Three distorted tetrahedral Dy(iii) aryloxide complexes, [Na(THF)(6)][Dy(OAr(Ad(2)tBu))(2)Cl(2)] (1) (OAr(Ad(2)tBu) = OC(6)H(2)Adamantyl(2)-2,6-(t)Bu-4) and [Na(THF)(6)][Dy(OMes*)(3)X] (X = Cl, 2; BH(4), 3), (OMes* = OC(6)H(2)(t)Bu(3)-2,4,6) exhibit easy axis magnetic anisotropy and slow magnetic relaxation at zero field, with relaxation rates 1 < 2 < 3. The Royal Society of Chemistry 2021-08-12 /pmc/articles/PMC8438701/ /pubmed/34519290 http://dx.doi.org/10.1039/d1cc02707g Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Parmar, Vijay S.
Gransbury, Gemma K.
Whitehead, George F. S.
Mills, David P.
Winpenny, Richard E. P.
Slow magnetic relaxation in distorted tetrahedral Dy(iii) aryloxide complexes
title Slow magnetic relaxation in distorted tetrahedral Dy(iii) aryloxide complexes
title_full Slow magnetic relaxation in distorted tetrahedral Dy(iii) aryloxide complexes
title_fullStr Slow magnetic relaxation in distorted tetrahedral Dy(iii) aryloxide complexes
title_full_unstemmed Slow magnetic relaxation in distorted tetrahedral Dy(iii) aryloxide complexes
title_short Slow magnetic relaxation in distorted tetrahedral Dy(iii) aryloxide complexes
title_sort slow magnetic relaxation in distorted tetrahedral dy(iii) aryloxide complexes
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8438701/
https://www.ncbi.nlm.nih.gov/pubmed/34519290
http://dx.doi.org/10.1039/d1cc02707g
work_keys_str_mv AT parmarvijays slowmagneticrelaxationindistortedtetrahedraldyiiiaryloxidecomplexes
AT gransburygemmak slowmagneticrelaxationindistortedtetrahedraldyiiiaryloxidecomplexes
AT whiteheadgeorgefs slowmagneticrelaxationindistortedtetrahedraldyiiiaryloxidecomplexes
AT millsdavidp slowmagneticrelaxationindistortedtetrahedraldyiiiaryloxidecomplexes
AT winpennyrichardep slowmagneticrelaxationindistortedtetrahedraldyiiiaryloxidecomplexes

Ejemplares similares