A dicoordinate gold(i)–ethylene complex

The use of the exceptionally bulky tris-2-(4,4′-di-tert-butylbiphenylyl)phosphine ligand allows the isolation and complete characterization of the first dicoordinate gold(i)–ethylene adduct, filling a missing fundamental piece on the organometallic chemistry of gold. Besides, the bonding situation o...

Descripción completa

Detalles Bibliográficos
Autores principales: Navarro, Miquel, Miranda-Pizarro, Juan, Moreno, Juan J., Navarro-Gilabert, Carlos, Fernández, Israel, Campos, Jesús
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8438763/
https://www.ncbi.nlm.nih.gov/pubmed/34519292
http://dx.doi.org/10.1039/d1cc02769g
_version_ 1783752408817467392
author Navarro, Miquel
Miranda-Pizarro, Juan
Moreno, Juan J.
Navarro-Gilabert, Carlos
Fernández, Israel
Campos, Jesús
author_facet Navarro, Miquel
Miranda-Pizarro, Juan
Moreno, Juan J.
Navarro-Gilabert, Carlos
Fernández, Israel
Campos, Jesús
author_sort Navarro, Miquel
collection PubMed
description The use of the exceptionally bulky tris-2-(4,4′-di-tert-butylbiphenylyl)phosphine ligand allows the isolation and complete characterization of the first dicoordinate gold(i)–ethylene adduct, filling a missing fundamental piece on the organometallic chemistry of gold. Besides, the bonding situation of this species has been investigated by means of state-of-the-art Density Functional Theory (DFT) calculations indicating that π-backdonation plays a minor role compared with tricoordinate analogues.
format Online
Article
Text
id pubmed-8438763
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-84387632021-09-27 A dicoordinate gold(i)–ethylene complex Navarro, Miquel Miranda-Pizarro, Juan Moreno, Juan J. Navarro-Gilabert, Carlos Fernández, Israel Campos, Jesús Chem Commun (Camb) Chemistry The use of the exceptionally bulky tris-2-(4,4′-di-tert-butylbiphenylyl)phosphine ligand allows the isolation and complete characterization of the first dicoordinate gold(i)–ethylene adduct, filling a missing fundamental piece on the organometallic chemistry of gold. Besides, the bonding situation of this species has been investigated by means of state-of-the-art Density Functional Theory (DFT) calculations indicating that π-backdonation plays a minor role compared with tricoordinate analogues. The Royal Society of Chemistry 2021-08-11 /pmc/articles/PMC8438763/ /pubmed/34519292 http://dx.doi.org/10.1039/d1cc02769g Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Navarro, Miquel
Miranda-Pizarro, Juan
Moreno, Juan J.
Navarro-Gilabert, Carlos
Fernández, Israel
Campos, Jesús
A dicoordinate gold(i)–ethylene complex
title A dicoordinate gold(i)–ethylene complex
title_full A dicoordinate gold(i)–ethylene complex
title_fullStr A dicoordinate gold(i)–ethylene complex
title_full_unstemmed A dicoordinate gold(i)–ethylene complex
title_short A dicoordinate gold(i)–ethylene complex
title_sort dicoordinate gold(i)–ethylene complex
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8438763/
https://www.ncbi.nlm.nih.gov/pubmed/34519292
http://dx.doi.org/10.1039/d1cc02769g
work_keys_str_mv AT navarromiquel adicoordinategoldiethylenecomplex
AT mirandapizarrojuan adicoordinategoldiethylenecomplex
AT morenojuanj adicoordinategoldiethylenecomplex
AT navarrogilabertcarlos adicoordinategoldiethylenecomplex
AT fernandezisrael adicoordinategoldiethylenecomplex
AT camposjesus adicoordinategoldiethylenecomplex
AT navarromiquel dicoordinategoldiethylenecomplex
AT mirandapizarrojuan dicoordinategoldiethylenecomplex
AT morenojuanj dicoordinategoldiethylenecomplex
AT navarrogilabertcarlos dicoordinategoldiethylenecomplex
AT fernandezisrael dicoordinategoldiethylenecomplex
AT camposjesus dicoordinategoldiethylenecomplex

Ejemplares similares