Cargando…

An in situ masking strategy enables radical monodecarboxylative C–C bond coupling of malonic acid derivatives

The utilization of malonic acids in radical decarboxylative functionalization is still underexploited, and the few existing examples are primarily limited to bisdecarboxylative functionalization. While radical monodecarboxylative functionalization is highly desirable, it is challenging because of th...

Descripción completa

Detalles Bibliográficos
Autores principales:	Cheng, He-Li, Xie, Xian-Hui, Chen, Jia-Zheng, Wang, Zhen, Chen, Jian-Ping
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2021
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8442682/ https://www.ncbi.nlm.nih.gov/pubmed/34659716 http://dx.doi.org/10.1039/d1sc02642a

Ejemplares similares

Catalytic three-component C–C bond forming dearomatization of bromoarenes with malonates and diazo compounds
por: Kato, Hiroki, et al.
Publicado: (2020)

Selective C–O bond formation via a photocatalytic radical coupling strategy: access to perfluoroalkoxylated (OR(F)) arenes and heteroarenes
por: Lee, Johnny W., et al.
Publicado: (2017)

Benzylic C(sp(3))–C(sp(2)) cross-coupling of indoles enabled by oxidative radical generation and nickel catalysis
por: Kim, Weonjeong, et al.
Publicado: (2021)

Radical generation enabled by photoinduced N–O bond fragmentation
por: McClain, Edward J., et al.
Publicado: (2022)

Palladium-catalyzed direct asymmetric C–H bond functionalization enabled by the directing group strategy
por: Yang, Ke, et al.
Publicado: (2020)

Pyridine-enabled copper-promoted cross dehydrogenative coupling of C(sp(2))–H and unactivated C(sp(3))–H bonds
por: Wu, Xuesong, et al.
Publicado: (2015)

Photocatalytic C(sp(3)) radical generation via C–H, C–C, and C–X bond cleavage
por: Huang, Chia-Yu, et al.
Publicado: (2022)

Synthesis of chiral malonates by α-alkylation of 2,2-diphenylethyl tert-butyl malonates via enantioselective phase-transfer catalysis
por: Guo, Zhibin, et al.
Publicado: (2023)

Site-selective coupling of remote C(sp(3))–H/meta-C(sp(2))–H bonds enabled by Ru/photoredox dual catalysis and mechanistic studies
por: Liu, Hong-Chao, et al.
Publicado: (2022)

New avenues for C–B bond formation via radical intermediates
por: Friese, Florian W., et al.
Publicado: (2019)

Recent application of visible-light induced radicals in C–S bond formation
por: Srivastava, Vishal, et al.
Publicado: (2020)

Sulfamides direct radical-mediated chlorination of aliphatic C–H bonds
por: Short, Melanie A., et al.
Publicado: (2019)

Electrochemical radical-mediated selective C(sp(3))–S bond activation
por: Li, Yongli, et al.
Publicado: (2022)

Unstrained C–C bond activation and directed fluorination through photocatalytically-generated radical cations
por: Pitts, Cody Ross, et al.
Publicado: (2015)

Reactions of triosmium and triruthenium clusters with 2-ethynylpyridine: new modes for alkyne C–C bond coupling and C–H bond activation
por: Joy, Md. Tuhinur R., et al.
Publicado: (2020)

Discovery of C—C bond-forming and bond-breaking radical enzymes: enabling transformations for metabolic engineering
por: Fu, Beverly, et al.
Publicado: (2020)

Chain propagation determines the chemo- and regioselectivity of alkyl radical additions to C–O vs. C–C double bonds
por: Paulisch, Tiffany O., et al.
Publicado: (2019)

Base-Promoted C–C Bond Activation Enables Radical Allylation with Homoallylic Alcohols
por: Lübbesmeyer, Maximilian, et al.
Publicado: (2020)

Direct, stereoselective thioglycosylation enabled by an organophotoredox radical strategy
por: Ji, Peng, et al.
Publicado: (2020)

Iron-catalyzed tandem reaction of C–Se bond coupling/selenosulfonation of indols with benzeneselenols
por: Guan, Senling, et al.
Publicado: (2020)

Organocopper cross-coupling reaction for C–C bond formation on highly sterically hindered structures
por: Oi, Miku, et al.
Publicado: (2019)

Metal-free C–C bond formation via coupling of nitrile imines and boronic acids
por: Livingstone, Keith, et al.
Publicado: (2019)

Cobalt-catalyzed intramolecular decarbonylative coupling of acylindoles and diarylketones through the cleavage of C–C bonds
por: Yu, Tian-Yang, et al.
Publicado: (2020)

Mechanistic insights into the S(N)2-type reactivity of aryl-Co(iii) masked-carbenes for C–C bond forming transformations
por: Planas, O., et al.
Publicado: (2018)

Cell-free protein synthesis and in situ immobilization of deGFP-MatB in polymer microgels for malonate-to-malonyl CoA conversion
por: Köhler, Tony, et al.
Publicado: (2020)

Enabling Cyclization Strategies through Carbonyl-Ylide-Mediated Synthesis of Malonate Enol Ethers
por: Viñas-Lóbez, Júlia, et al.
Publicado: (2021)

Decarboxylative cross-coupling reactions for P(O)–C bond formation
por: Hosseinian, Akram, et al.
Publicado: (2018)

Nucleophile promoted gold redox catalysis with diazonium salts: C–Br, C–S and C–P bond formation through catalytic Sandmeyer coupling
por: Peng, Haihui, et al.
Publicado: (2016)

Enantioselective palladium/copper-catalyzed C–C σ-bond activation synergized with Sonogashira-type C(sp(3))–C(sp) cross-coupling alkynylation
por: Sun, Feng-Na, et al.
Publicado: (2019)

A visible-light-promoted radical reaction system for azidation and halogenation of tertiary aliphatic C–H bonds
por: Wang, Yaxin, et al.
Publicado: (2016)

A new face of phenalenyl-based radicals in the transition metal-free C–H arylation of heteroarenes at room temperature: trapping the radical initiator via C–C σ-bond formation
por: Ahmed, Jasimuddin, et al.
Publicado: (2017)

C–H functionalization reactions enabled by hydrogen atom transfer to carbon-centered radicals
por: Sarkar, Sumon, et al.
Publicado: (2020)

A synergistic LUMO lowering strategy using Lewis acid catalysis in water to enable photoredox catalytic, functionalizing C–C cross-coupling of styrenes
por: Speckmeier, Elisabeth, et al.
Publicado: (2018)

Enzyme-catalyzed synthesis of malonate polyesters and their use as metal chelating materials
por: Byrne, Fergal P., et al.
Publicado: (2021)

An experimental and theoretical charge density study of theophylline and malonic acid cocrystallization
por: Hawkins, Bryson A., et al.
Publicado: (2022)

Metal-free visible-induced C(sp(2))–C(sp(2)) coupling of quinoxalin-2(H)-ones via oxidative cleavage of the C–N bond
por: Wu, Mei, et al.
Publicado: (2023)

Nickel catalysis enables convergent paired electrolysis for direct arylation of benzylic C–H bonds
por: Zhang, Lei, et al.
Publicado: (2020)

Aryl diazonium intermediates enable mild DNA-compatible C–C bond formation for medicinally relevant combinatorial library synthesis
por: Li, Xianfeng, et al.
Publicado: (2022)

The formyloxyl radical: electrophilicity, C–H bond activation and anti-Markovnikov selectivity in the oxidation of aliphatic alkenes
por: Somekh, Miriam, et al.
Publicado: (2020)

A walk around the application of nanocatalysts for cross-dehydrogenative coupling of C–H bonds
por: Wang, Jianjie, et al.
Publicado: (2019)

Cannot write session to /tmp/vufind_sessions/sess_au26ued9ej6n0vfnlps4mvqvv3