Cargando…

Synthesis of hydrosilylboronates via the monoborylation of a dihydrosilane Si–H bond and their application for the generation of dialkylhydrosilyl anions

The synthesis of a series of hydrosilylboronates via the selective iridium- or nickel-catalyzed monoborylation of dihydrosilane Si–H bonds is described. The synthesized silylboronates, which bear a single Si–H bond, can be used as novel silicon nucleophiles in the presence of transition-metal cataly...

Descripción completa

Detalles Bibliográficos
Autores principales: Takeuchi, Takumi, Shishido, Ryosuke, Kubota, Koji, Ito, Hajime
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8442725/
https://www.ncbi.nlm.nih.gov/pubmed/34659718
http://dx.doi.org/10.1039/d1sc01440d

Ejemplares similares