Cargando…
Highly Efficient Removal for Methylene Blue and Cu(2+) onto UiO-66 Metal–Organic Framework/Carboxylated Graphene Oxide-Incorporated Sodium Alginate Beads
[Image: see text] Herein, we report a new metal–organic framework (MOF)-based composite beads adsorbent made via incorporating UiO-66 MOF, carboxylated graphene oxide (GOCOOH) into sodium alginate for efficient removal of methylene blue dye, and Cu(2+) ions. The successful fabrication of the synthes...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2021
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8444308/ https://www.ncbi.nlm.nih.gov/pubmed/34549149 http://dx.doi.org/10.1021/acsomega.1c03479 |
Sumario: | [Image: see text] Herein, we report a new metal–organic framework (MOF)-based composite beads adsorbent made via incorporating UiO-66 MOF, carboxylated graphene oxide (GOCOOH) into sodium alginate for efficient removal of methylene blue dye, and Cu(2+) ions. The successful fabrication of the synthesized UiO-66/GOCOOH@SA composite beads was confirmed by means of X-ray diffraction, Fourier transform infrared, scanning electron microscopy, zeta potential, X-ray photoelectron spectroscopy analysis, and thermogravimetric analysis and BET measurement. The incorporation of both UiO-66 and GOCOOH into SA beads greatly increased their adsorption efficiency for the removal of both MB and Cu(2+) with maximum adsorption capacities of 490.72 and 343.49 mg/g, respectively. The removal process of both MB and Cu(2+) follows the pseudo-second-order model and Freundlich isotherm model. A plausible adsorption mechanism was discussed in detail. Regeneration tests clarified that the removal efficiencies toward both MB and Cu(2+) remained higher than 87% after five cycles. These results reveal the potentiality of UiO-66/GOCOOH@SA beads as an excellent adsorbent. |
---|