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Synthesis and Oligonuclear Structures of Strontium and Barium Complexes with Protonated and Deprotonated N-Mesityl-P,P-diphenylphosphinic Amide Ligands
[Image: see text] Metalation of N-mesityl-P,P-diphenylphosphinic amide Ph(2)P(O)-NHMes (HL, I) with MgBu(2) and Ae{N(SiMe(3))(2)}(2) (Ae = Ca, Sr, and Ba) yields alkaline-earth metal complexes with the compositions of [(thf)(n)Ae(L·HL)(2)] [Ae/n = Mg/0 (II), Ca/2 (III)] as well as of [Sr(2)L(3)(L·HL...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8444311/ https://www.ncbi.nlm.nih.gov/pubmed/34549155 http://dx.doi.org/10.1021/acsomega.1c03732 |