Efficient Exchange in a Bioinspired Dynamic Covalent Polymer Network via a Cyclic Phosphate Triester Intermediate

[Image: see text] Bond exchange via neighboring group-assisted reactions in dynamic covalent networks results in efficient mechanical relaxation. In Nature, the high reactivity of RNA toward nucleophilic substitution is largely attributed to the formation of a cyclic phosphate ester intermediate via...

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Detalles Bibliográficos
Autores principales: Majumdar, Soumabrata, Mezari, Brahim, Zhang, Huiyi, van Aart, Jeroen, van Benthem, Rolf A. T. M., Heuts, Johan P. A., Sijbesma, Rint P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8444552/
https://www.ncbi.nlm.nih.gov/pubmed/34552277
http://dx.doi.org/10.1021/acs.macromol.1c01504

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