Adenine Radical Cation Formation by a Ligand-Centered Excited State of an Intercalated Chromium Polypyridyl Complex Leads to Enhanced DNA Photo-oxidation

[Image: see text] Assessment of the DNA photo-oxidation and synthetic photocatalytic activity of chromium polypyridyl complexes is dominated by consideration of their long-lived metal-centered excited states. Here we report the participation of the excited states of [Cr(TMP)(2)dppz](3+) (1) (TMP = 3...

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Detalles Bibliográficos
Autores principales: Baptista, Frederico A., Krizsan, Dorottya, Stitch, Mark, Sazanovich, Igor V., Clark, Ian P., Towrie, Michael, Long, Conor, Martinez-Fernandez, Lara, Improta, Roberto, Kane-Maguire, Noel A. P., Kelly, John M., Quinn, Susan J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8447253/
https://www.ncbi.nlm.nih.gov/pubmed/34464120
http://dx.doi.org/10.1021/jacs.1c06658

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8447253/
https://www.ncbi.nlm.nih.gov/pubmed/34464120
http://dx.doi.org/10.1021/jacs.1c06658

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