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Hydrogenative coupling of nitriles with diamines to benzimidazoles using lignin-derived Rh(2)P catalyst

Nitrile (C≡N bond) activation for direct organic synthesis has been less explored so far due to a high redox potential of nitrile and its low dissociation energy of C−CN bond. Herein, we demonstrate a direct reductive coupling of nitriles and 1,2-phenylenediamines to yield various benzimidazoles in...

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Detalles Bibliográficos
Autores principales:	Zhang, Jiarui, Yao, Ruxu, Chen, Jinzhu, Li, Tao, Xu, Yisheng
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Elsevier 2021
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8450259/ https://www.ncbi.nlm.nih.gov/pubmed/34585110 http://dx.doi.org/10.1016/j.isci.2021.103045

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