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Photoredox catalysis in nickel-catalyzed C–H functionalization
Catalytic C‒H functionalization has become a powerful strategy in organic synthesis due to the improved atom-, step- and resource economy in comparison with cross-coupling or classical organic functional group transformations. Despite the significant advances in the metal-catalyzed C‒H activations,...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8451005/ https://www.ncbi.nlm.nih.gov/pubmed/34621388 http://dx.doi.org/10.3762/bjoc.17.143 |
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author | Mantry, Lusina Maayuri, Rajaram Kumar, Vikash Gandeepan, Parthasarathy |
author_facet | Mantry, Lusina Maayuri, Rajaram Kumar, Vikash Gandeepan, Parthasarathy |
author_sort | Mantry, Lusina |
collection | PubMed |
description | Catalytic C‒H functionalization has become a powerful strategy in organic synthesis due to the improved atom-, step- and resource economy in comparison with cross-coupling or classical organic functional group transformations. Despite the significant advances in the metal-catalyzed C‒H activations, recent developments in the field of metallaphotoredox catalysis enabled C‒H functionalizations with unique reaction pathways under mild reaction conditions. Given the relative earth-abundance and cost-effective nature, nickel catalysts for photoredox C‒H functionalization have received significant attention. In this review, we highlight the developments in the field of photoredox nickel-catalyzed C‒H functionalization reactions with a range of applications until summer 2021. |
format | Online Article Text |
id | pubmed-8451005 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | Beilstein-Institut |
record_format | MEDLINE/PubMed |
spelling | pubmed-84510052021-10-06 Photoredox catalysis in nickel-catalyzed C–H functionalization Mantry, Lusina Maayuri, Rajaram Kumar, Vikash Gandeepan, Parthasarathy Beilstein J Org Chem Review Catalytic C‒H functionalization has become a powerful strategy in organic synthesis due to the improved atom-, step- and resource economy in comparison with cross-coupling or classical organic functional group transformations. Despite the significant advances in the metal-catalyzed C‒H activations, recent developments in the field of metallaphotoredox catalysis enabled C‒H functionalizations with unique reaction pathways under mild reaction conditions. Given the relative earth-abundance and cost-effective nature, nickel catalysts for photoredox C‒H functionalization have received significant attention. In this review, we highlight the developments in the field of photoredox nickel-catalyzed C‒H functionalization reactions with a range of applications until summer 2021. Beilstein-Institut 2021-08-31 /pmc/articles/PMC8451005/ /pubmed/34621388 http://dx.doi.org/10.3762/bjoc.17.143 Text en Copyright © 2021, Mantry et al. https://creativecommons.org/licenses/by/4.0/https://www.beilstein-journals.org/bjoc/terms/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0 (https://creativecommons.org/licenses/by/4.0/) ). Please note that the reuse, redistribution and reproduction in particular requires that the author(s) and source are credited and that individual graphics may be subject to special legal provisions. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms/terms) |
spellingShingle | Review Mantry, Lusina Maayuri, Rajaram Kumar, Vikash Gandeepan, Parthasarathy Photoredox catalysis in nickel-catalyzed C–H functionalization |
title | Photoredox catalysis in nickel-catalyzed C–H functionalization |
title_full | Photoredox catalysis in nickel-catalyzed C–H functionalization |
title_fullStr | Photoredox catalysis in nickel-catalyzed C–H functionalization |
title_full_unstemmed | Photoredox catalysis in nickel-catalyzed C–H functionalization |
title_short | Photoredox catalysis in nickel-catalyzed C–H functionalization |
title_sort | photoredox catalysis in nickel-catalyzed c–h functionalization |
topic | Review |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8451005/ https://www.ncbi.nlm.nih.gov/pubmed/34621388 http://dx.doi.org/10.3762/bjoc.17.143 |
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