Accessing Improbable Foldamer Shapes with Strained Macrocycles

The alkylation of some secondary amide functions with a dimethoxybenzyl (DMB) group in oligomers of 8‐amino‐2‐quinolinecarboxylic acid destabilizes the otherwise favored helical conformations, and allows for cyclization to take place. A cyclic hexamer and a cyclic heptamer were produced in this mann...

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Detalles Bibliográficos
Autores principales: Urushibara, Ko, Ferrand, Yann, Liu, Zhiwei, Katagiri, Kosuke, Kawahata, Masatoshi, Morvan, Estelle, D'Elia, Ryan, Pophristic, Vojislava, Tanatani, Aya, Huc, Ivan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8453500/
https://www.ncbi.nlm.nih.gov/pubmed/33905165
http://dx.doi.org/10.1002/chem.202101201

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8453500/
https://www.ncbi.nlm.nih.gov/pubmed/33905165
http://dx.doi.org/10.1002/chem.202101201

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