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Preparation of Butadienylpyridines by Iridium‐NHC‐Catalyzed Alkyne Hydroalkenylation and Quinolizine Rearrangement

Iridium(I) N‐heterocyclic carbene complexes of formula Ir(κ(2) O,O’‐BHetA)(IPr)(η (2)‐coe) [BHetA=bis‐heteroatomic acidato, acetylacetonate or acetate; IPr=1,3‐bis(2,6‐diisopropylphenyl)imidazolin‐2‐carbene; coe=cyclooctene] have been prepared by treating Ir(κ(2) O,O’‐BHetA)(η (2)‐coe)(2) complexes...

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Detalles Bibliográficos
Autores principales: Azpíroz, Ramón, Greger, Ingo, Oro, Luis A., Passarelli, Vincenzo, Castarlenas, Ricardo, Pérez‐Torrente, Jesús J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8453560/
https://www.ncbi.nlm.nih.gov/pubmed/33998070
http://dx.doi.org/10.1002/chem.202101414