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Origin of Increased Reactivity in Rhenium-Mediated Cycloadditions of Tetrazines
[Image: see text] Pyridyl tetrazines coordinated to metals like rhenium have been shown to be more reactive in [4 + 2] cycloadditions than their uncomplexed counterparts. Using density functional theory calculations, we found a more favorable interaction energy caused by stronger orbital interaction...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8453624/ https://www.ncbi.nlm.nih.gov/pubmed/34468143 http://dx.doi.org/10.1021/acs.joc.1c01564 |