Cargando…

Rethinking Borole Cycloaddition Reactivity

Boroles are attracting broad interest for their myriad and diverse applications, including in synthesis, small molecule activation and functional materials. Their properties and reactivity are closely linked to the cyclic conjugated diene system, which has been shown to participate in cycloaddition...

Descripción completa

Detalles Bibliográficos
Autores principales:	Lindl, Felix, Guo, Xueying, Krummenacher, Ivo, Rauch, Florian, Rempel, Anna, Paprocki, Valerie, Dellermann, Theresa, Stennett, Tom E., Lamprecht, Anna, Brückner, Tobias, Radacki, Krzysztof, Bélanger‐Chabot, Guillaume, Marder, Todd B., Lin, Zhenyang, Braunschweig, Holger
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8453799/ https://www.ncbi.nlm.nih.gov/pubmed/34008250 http://dx.doi.org/10.1002/chem.202101290

Ejemplares similares

Boroles from alumoles: accessing boroles with alkyl-substituted backbones via transtrielation
por: Bohlen, Josina L., et al.
Publicado: (2023)

Diboramacrocycles: reversible borole dimerisation–dissociation systems
por: Fuchs, Sonja, et al.
Publicado: (2022)

Phenylpyridyl‐Fused Boroles: A Unique Coordination Mode and Weak B−N Coordination‐Induced Dual Fluorescence
por: He, Jiang, et al.
Publicado: (2021)

(Hetero)arene-fused boroles: a broad spectrum of applications
por: He, Jiang, et al.
Publicado: (2020)

Rhodium‐Mediated Stoichiometric Synthesis of Mono‐, Bi‐, and Bis‐1,2‐Azaborinines: 1‐Rhoda‐3,2‐azaboroles as Reactive Precursors
por: Heß, Merlin, et al.
Publicado: (2021)

Dimeric boroles: effective sources of monomeric boroles for heterocycle synthesis
por: Su, Xiaojun, et al.
Publicado: (2019)

Taming the beast: fluoromesityl groups induce a dramatic stability enhancement in boroles
por: Zhang, Zuolun, et al.
Publicado: (2015)

Synthesis of Boron Analogues of Enamines via Hydroamination of a Boron−Boron Triple Bond
por: Brückner, Tobias, et al.
Publicado: (2020)

A Cationic NHC‐Supported Borole
por: Heitkemper, Tobias, et al.
Publicado: (2020)

Isolation of Neutral, Mono‐, and Dicationic B(2)P(2) Rings by Diphosphorus Addition to a Boron−Boron Triple Bond
por: Brückner, Tobias, et al.
Publicado: (2021)

Reduction and Rearrangement of a Boron(I) Carbonyl Complex
por: Rang, Maximilian, et al.
Publicado: (2020)

Reactions of diborenes with terminal alkynes: mechanisms of ligand-controlled anti-selective hydroalkynylation, cycloaddition and C[triple bond, length as m-dash]C triple bond scission
por: Englert, Lukas, et al.
Publicado: (2021)

Backbone-controlled LUMO energy induces intramolecular C–H activation in ortho-bis-9-borafluorene-substituted phenyl and o-carboranyl compounds leading to novel 9,10-diboraanthracene derivatives
por: Krebs, Johannes, et al.
Publicado: (2022)

Mild synthesis of diboryldiborenes by diboration of B–B triple bonds
por: Brückner, Tobias, et al.
Publicado: (2019)

Alkene insertion reactivity of a o-carboranyl-substituted 9-borafluorene
por: Bischof, Tobias, et al.
Publicado: (2022)

Oxidation, Coordination, and Nickel‐Mediated Deconstruction of a Highly Electron‐Rich Diboron Analogue of 1,3,5‐Hexatriene
por: Hermann, Alexander, et al.
Publicado: (2020)

Highly Stable, Readily Reducible, Fluorescent, Trifluoromethylated 9‐Borafluorenes
por: Rauch, Florian, et al.
Publicado: (2020)

Adducts of the Parent Boraphosphaketene H(2)BPCO and their Decarbonylative Insertion Chemistry
por: Hagspiel, Stephan, et al.
Publicado: (2021)

Reduction of a dihydroboryl cation to a boryl anion and its air-stable, neutral hydroboryl radical through hydrogen shuttling
por: Hagspiel, Stephan, et al.
Publicado: (2019)

Electronically Driven Regioselective Iridium‐Catalyzed C−H Borylation of Donor‐π‐Acceptor Chromophores Containing Triarylboron Acceptors
por: Rauch, Florian, et al.
Publicado: (2020)

N‐Heterocyclic Olefins as Electron Donors in Combination with Triarylborane Acceptors: Synthesis, Optical and Electronic Properties of D–π–A Compounds
por: He, Jiang, et al.
Publicado: (2019)

Reactivity of cyano- and isothiocyanatoborylenes: metal coordination, one-electron oxidation and boron-centred Brønsted basicity
por: Hagspiel, Stephan, et al.
Publicado: (2021)

An Iterative Divergent Approach to Conjugated Starburst Borane Dendrimers
por: Rauch, Florian, et al.
Publicado: (2020)

Disclosing Cyclic(Alkyl)(Amino)Carbenes as One‐Electron Reductants: Synthesis of Acyclic(Amino)(Aryl)Carbene‐Based Kekulé Diradicaloids
por: Maiti, Avijit, et al.
Publicado: (2022)

Hexahalodiborate Dianions: A New Family of Binary Boron Halides
por: Bélanger‐Chabot, Guillaume, et al.
Publicado: (2019)

Ring expansion of alumoles with organic azides: selective formation of six-membered aluminum–nitrogen heterocycles
por: Drescher, Regina, et al.
Publicado: (2020)

Steric Effects Dictate the Formation of Terminal Arylborylene Complexes of Ruthenium from Dihydroboranes
por: Lenczyk, Carsten, et al.
Publicado: (2019)

Electron‐Rich EDOT Linkers in Tetracationic bis‐Triarylborane Chromophores: Influence on Water Stability, Biomacromolecule Sensing, and Photoinduced Cytotoxicity
por: Ferger, Matthias, et al.
Publicado: (2022)

Synthesis and Structure of an o‐Carboranyl‐Substituted Three‐Coordinate Borane Radical Anion
por: Krebs, Johannes, et al.
Publicado: (2021)

Computationally Guided Molecular Design to Minimize the LE/CT Gap in D‐π‐A Fluorinated Triarylboranes for Efficient TADF via D and π‐Bridge Tuning
por: Narsaria, Ayush K., et al.
Publicado: (2020)

Hydrophosphination of boron–boron multiple bonds
por: Stennett, Tom E., et al.
Publicado: (2019)

Base‐Mediated Radical Borylation of Alkyl Sulfones
por: Huang, Mingming, et al.
Publicado: (2021)

Synthesis, Characterization, In Vitro and In Vivo Screening of Unsymmetrical Borole Complexes of 2-Hydroxy-N-Phenylbenzamide and its Derivatives
por: Pandey, Taruna, et al.
Publicado: (2000)

2-(3-Methoxyphenyl)-1,3-dihydro-1,3,2-benzodiazaborole
por: Robinson, Ross S., et al.
Publicado: (2012)

A donor-supported silavinylidene and silylium ylides: boroles as a flexible platform for versatile Si(ii) chemistry
por: Sarcevic, Julijan, et al.
Publicado: (2023)

Synthesis, Photophysical and Electronic Properties of Mono‐, Di‐, and Tri‐Amino‐Substituted Ortho‐Perylenes, and Comparison to the Tetra‐Substituted Derivative
por: Merz, Julia, et al.
Publicado: (2020)

Crystal structure of (3S*,4R*)-4-fluoro-3-(4-methoxyphenyl)-1-oxo-2-phenyl-1,2,3,4-tetrahydroisoquinoline-4-carboxylic acid
por: Lehmann, Anna, et al.
Publicado: (2017)

Isolation of diborenes and their 90°-twisted diradical congeners
por: Böhnke, Julian, et al.
Publicado: (2018)

Side-on coordination of boryl and borylene complexes to cationic coinage metal fragments
por: Braunschweig, Holger, et al.
Publicado: (2015)

Highly Colored Boron‐Doped Thiazolothiazoles from the Reductive Dimerization of Boron Isothiocyanates
por: Hagspiel, Stephan, et al.
Publicado: (2021)

Cannot write session to /tmp/vufind_sessions/sess_ghkdfeos6jidu5c5peai9mkcqj