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1,3‐Bis(tricyanoborane)imidazoline‐2‐ylidenate Anion—A Ditopic Dianionic N‐Heterocyclic Carbene Ligand
The 1,3‐bis(tricyanoborane)imidazolate anion 1 was obtained in high yield from lithium imidazolate and B(CN)(3)−pyridine adduct. Anion 1 is chemically very robust and thus allowed the isolation of the corresponding H(5)O(2) (+) salt. Furthermore, monoanion 1 served as starting species for the novel...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8453866/ https://www.ncbi.nlm.nih.gov/pubmed/33961330 http://dx.doi.org/10.1002/anie.202105529 |