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Electrolyte Design for Lithium Metal Anode‐Based Batteries Toward Extreme Temperature Application
Lithium anode‐based batteries (LBs) are highly demanded in society owing to the high theoretical capacity and low reduction potential of metallic lithium. They are expected to see increasing deployment in performance critical areas including electric vehicles, grid storage, space, and sea vehicle op...
Autores principales: | , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456284/ https://www.ncbi.nlm.nih.gov/pubmed/34272930 http://dx.doi.org/10.1002/advs.202101051 |
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author | Luo, Dan Li, Matthew Zheng, Yun Ma, Qianyi Gao, Rui Zhang, Zhen Dou, Haozhen Wen, Guobin Shui, Lingling Yu, Aiping Wang, Xin Chen, Zhongwei |
author_facet | Luo, Dan Li, Matthew Zheng, Yun Ma, Qianyi Gao, Rui Zhang, Zhen Dou, Haozhen Wen, Guobin Shui, Lingling Yu, Aiping Wang, Xin Chen, Zhongwei |
author_sort | Luo, Dan |
collection | PubMed |
description | Lithium anode‐based batteries (LBs) are highly demanded in society owing to the high theoretical capacity and low reduction potential of metallic lithium. They are expected to see increasing deployment in performance critical areas including electric vehicles, grid storage, space, and sea vehicle operations. Unfortunately, competitive performance cannot be achieved when LBs operating under extreme temperature conditions where the lithium‐ion chemistry fail to perform optimally. In this review, a brief overview of the challenges in developing LBs for low temperature (<0 °C) and high temperature (>60 °C) operation are provided followed by electrolyte design strategies involving Li salt modification, solvation structure optimization, additive introduction, and solid‐state electrolyte utilization for LBs are introduced. Specifically, the prospects of using lithium metal batteries (LMBs), lithium sulfur (Li‐S) batteries, and lithium oxygen (Li‐O(2)) batteries for performance under low and high temperature applications are evaluated. These three chemistries are presented as prototypical examples of how the conventional low temperature charge transfer resistances and high temperature side reactions can be overcome. This review also points out the research direction of extreme temperature electrolyte design toward practical applications. |
format | Online Article Text |
id | pubmed-8456284 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | John Wiley and Sons Inc. |
record_format | MEDLINE/PubMed |
spelling | pubmed-84562842021-09-27 Electrolyte Design for Lithium Metal Anode‐Based Batteries Toward Extreme Temperature Application Luo, Dan Li, Matthew Zheng, Yun Ma, Qianyi Gao, Rui Zhang, Zhen Dou, Haozhen Wen, Guobin Shui, Lingling Yu, Aiping Wang, Xin Chen, Zhongwei Adv Sci (Weinh) Reviews Lithium anode‐based batteries (LBs) are highly demanded in society owing to the high theoretical capacity and low reduction potential of metallic lithium. They are expected to see increasing deployment in performance critical areas including electric vehicles, grid storage, space, and sea vehicle operations. Unfortunately, competitive performance cannot be achieved when LBs operating under extreme temperature conditions where the lithium‐ion chemistry fail to perform optimally. In this review, a brief overview of the challenges in developing LBs for low temperature (<0 °C) and high temperature (>60 °C) operation are provided followed by electrolyte design strategies involving Li salt modification, solvation structure optimization, additive introduction, and solid‐state electrolyte utilization for LBs are introduced. Specifically, the prospects of using lithium metal batteries (LMBs), lithium sulfur (Li‐S) batteries, and lithium oxygen (Li‐O(2)) batteries for performance under low and high temperature applications are evaluated. These three chemistries are presented as prototypical examples of how the conventional low temperature charge transfer resistances and high temperature side reactions can be overcome. This review also points out the research direction of extreme temperature electrolyte design toward practical applications. John Wiley and Sons Inc. 2021-07-17 /pmc/articles/PMC8456284/ /pubmed/34272930 http://dx.doi.org/10.1002/advs.202101051 Text en © 2021 The Authors. Advanced Science published by Wiley‐VCH GmbH https://creativecommons.org/licenses/by/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. |
spellingShingle | Reviews Luo, Dan Li, Matthew Zheng, Yun Ma, Qianyi Gao, Rui Zhang, Zhen Dou, Haozhen Wen, Guobin Shui, Lingling Yu, Aiping Wang, Xin Chen, Zhongwei Electrolyte Design for Lithium Metal Anode‐Based Batteries Toward Extreme Temperature Application |
title | Electrolyte Design for Lithium Metal Anode‐Based Batteries Toward Extreme Temperature Application |
title_full | Electrolyte Design for Lithium Metal Anode‐Based Batteries Toward Extreme Temperature Application |
title_fullStr | Electrolyte Design for Lithium Metal Anode‐Based Batteries Toward Extreme Temperature Application |
title_full_unstemmed | Electrolyte Design for Lithium Metal Anode‐Based Batteries Toward Extreme Temperature Application |
title_short | Electrolyte Design for Lithium Metal Anode‐Based Batteries Toward Extreme Temperature Application |
title_sort | electrolyte design for lithium metal anode‐based batteries toward extreme temperature application |
topic | Reviews |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456284/ https://www.ncbi.nlm.nih.gov/pubmed/34272930 http://dx.doi.org/10.1002/advs.202101051 |
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