η(2)-Alkene Complexes of [Rh(PONOP-(i)Pr)(L)](+) Cations (L = COD, NBD, Ethene). Intramolecular Alkene-Assisted Hydrogenation and Dihydrogen Complex [Rh(PONOP-(i)Pr)(η-H(2))](+)

[Image: see text] Rhodium-alkene complexes of the pincer ligand κ(3)-C(5)H(3)N-2,6-(OP(i)Pr(2))(2) (PONOP-(i)Pr) have been prepared and structurally characterized: [Rh(PONOP-(i)Pr)(η(2)-alkene)][BAr(F)(4)] [alkene = cyclooctadiene (COD), norbornadiene (NBD), ethene; Ar(F) = 3,5-(CF(3))(2)C(6)H(3)]....

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Detalles Bibliográficos
Autores principales: Johnson, Alice, Royle, Cameron G., Brodie, Claire N., Martínez-Martínez, Antonio J., Duckett, Simon B., Weller, Andrew S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456414/
https://www.ncbi.nlm.nih.gov/pubmed/33570930
http://dx.doi.org/10.1021/acs.inorgchem.0c03687

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456414/
https://www.ncbi.nlm.nih.gov/pubmed/33570930
http://dx.doi.org/10.1021/acs.inorgchem.0c03687

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