Cargando…
Chemical Characterization of a Volatile Dubnium Compound, DbOCl(3)
The formation and the chemical characterization of single atoms of dubnium (Db, element 105), in the form of its volatile oxychloride, was investigated using the on‐line gas phase chromatography technique, in the temperature range 350–600 °C. Under the exactly same chemical conditions, comparative s...
| Autores principales: | , , , , , , , , , , , , , , , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456785/ https://www.ncbi.nlm.nih.gov/pubmed/33978998 http://dx.doi.org/10.1002/anie.202102808 |
| _version_ | 1784570937608241152 |
|---|---|
| author | Chiera, Nadine M. Sato, Tetsuya K. Eichler, Robert Tomitsuka, Tomohiro Asai, Masato Adachi, Sadia Dressler, Rugard Hirose, Kentaro Inoue, Hiroki Ito, Yuta Kashihara, Ayuna Makii, Hiroyuki Nishio, Katsuhisa Sakama, Minoru Shirai, Kaori Suzuki, Hayato Tokoi, Katsuyuki Tsukada, Kazuaki Watanabe, Eisuke Nagame, Yuichiro |
| author_facet | Chiera, Nadine M. Sato, Tetsuya K. Eichler, Robert Tomitsuka, Tomohiro Asai, Masato Adachi, Sadia Dressler, Rugard Hirose, Kentaro Inoue, Hiroki Ito, Yuta Kashihara, Ayuna Makii, Hiroyuki Nishio, Katsuhisa Sakama, Minoru Shirai, Kaori Suzuki, Hayato Tokoi, Katsuyuki Tsukada, Kazuaki Watanabe, Eisuke Nagame, Yuichiro |
| author_sort | Chiera, Nadine M. |
| collection | PubMed |
| description | The formation and the chemical characterization of single atoms of dubnium (Db, element 105), in the form of its volatile oxychloride, was investigated using the on‐line gas phase chromatography technique, in the temperature range 350–600 °C. Under the exactly same chemical conditions, comparative studies with the lighter homologues of Group 5 in the Periodic Table clearly indicate the volatility sequence being NbOCl(3) > TaOCl(3) ≥ DbOCl(3). From the obtained experimental results, thermochemical data for DbOCl(3) were derived. The present study delivers reliable experimental information for theoretical calculations on chemical properties of transactinides. |
| format | Online Article Text |
| id | pubmed-8456785 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2021 |
| publisher | John Wiley and Sons Inc. |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-84567852021-09-27 Chemical Characterization of a Volatile Dubnium Compound, DbOCl(3) Chiera, Nadine M. Sato, Tetsuya K. Eichler, Robert Tomitsuka, Tomohiro Asai, Masato Adachi, Sadia Dressler, Rugard Hirose, Kentaro Inoue, Hiroki Ito, Yuta Kashihara, Ayuna Makii, Hiroyuki Nishio, Katsuhisa Sakama, Minoru Shirai, Kaori Suzuki, Hayato Tokoi, Katsuyuki Tsukada, Kazuaki Watanabe, Eisuke Nagame, Yuichiro Angew Chem Int Ed Engl Communications The formation and the chemical characterization of single atoms of dubnium (Db, element 105), in the form of its volatile oxychloride, was investigated using the on‐line gas phase chromatography technique, in the temperature range 350–600 °C. Under the exactly same chemical conditions, comparative studies with the lighter homologues of Group 5 in the Periodic Table clearly indicate the volatility sequence being NbOCl(3) > TaOCl(3) ≥ DbOCl(3). From the obtained experimental results, thermochemical data for DbOCl(3) were derived. The present study delivers reliable experimental information for theoretical calculations on chemical properties of transactinides. John Wiley and Sons Inc. 2021-07-02 2021-08-09 /pmc/articles/PMC8456785/ /pubmed/33978998 http://dx.doi.org/10.1002/anie.202102808 Text en © 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ (https://creativecommons.org/licenses/by-nc-nd/4.0/) License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made. |
| spellingShingle | Communications Chiera, Nadine M. Sato, Tetsuya K. Eichler, Robert Tomitsuka, Tomohiro Asai, Masato Adachi, Sadia Dressler, Rugard Hirose, Kentaro Inoue, Hiroki Ito, Yuta Kashihara, Ayuna Makii, Hiroyuki Nishio, Katsuhisa Sakama, Minoru Shirai, Kaori Suzuki, Hayato Tokoi, Katsuyuki Tsukada, Kazuaki Watanabe, Eisuke Nagame, Yuichiro Chemical Characterization of a Volatile Dubnium Compound, DbOCl(3) |
| title | Chemical Characterization of a Volatile Dubnium Compound, DbOCl(3)
|
| title_full | Chemical Characterization of a Volatile Dubnium Compound, DbOCl(3)
|
| title_fullStr | Chemical Characterization of a Volatile Dubnium Compound, DbOCl(3)
|
| title_full_unstemmed | Chemical Characterization of a Volatile Dubnium Compound, DbOCl(3)
|
| title_short | Chemical Characterization of a Volatile Dubnium Compound, DbOCl(3)
|
| title_sort | chemical characterization of a volatile dubnium compound, dbocl(3) |
| topic | Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456785/ https://www.ncbi.nlm.nih.gov/pubmed/33978998 http://dx.doi.org/10.1002/anie.202102808 |
| work_keys_str_mv | AT chieranadinem chemicalcharacterizationofavolatiledubniumcompounddbocl3 AT satotetsuyak chemicalcharacterizationofavolatiledubniumcompounddbocl3 AT eichlerrobert chemicalcharacterizationofavolatiledubniumcompounddbocl3 AT tomitsukatomohiro chemicalcharacterizationofavolatiledubniumcompounddbocl3 AT asaimasato chemicalcharacterizationofavolatiledubniumcompounddbocl3 AT adachisadia chemicalcharacterizationofavolatiledubniumcompounddbocl3 AT dresslerrugard chemicalcharacterizationofavolatiledubniumcompounddbocl3 AT hirosekentaro chemicalcharacterizationofavolatiledubniumcompounddbocl3 AT inouehiroki chemicalcharacterizationofavolatiledubniumcompounddbocl3 AT itoyuta chemicalcharacterizationofavolatiledubniumcompounddbocl3 AT kashiharaayuna chemicalcharacterizationofavolatiledubniumcompounddbocl3 AT makiihiroyuki chemicalcharacterizationofavolatiledubniumcompounddbocl3 AT nishiokatsuhisa chemicalcharacterizationofavolatiledubniumcompounddbocl3 AT sakamaminoru chemicalcharacterizationofavolatiledubniumcompounddbocl3 AT shiraikaori chemicalcharacterizationofavolatiledubniumcompounddbocl3 AT suzukihayato chemicalcharacterizationofavolatiledubniumcompounddbocl3 AT tokoikatsuyuki chemicalcharacterizationofavolatiledubniumcompounddbocl3 AT tsukadakazuaki chemicalcharacterizationofavolatiledubniumcompounddbocl3 AT watanabeeisuke chemicalcharacterizationofavolatiledubniumcompounddbocl3 AT nagameyuichiro chemicalcharacterizationofavolatiledubniumcompounddbocl3 |