Cargando…

Site‐ and Enantioselective Iridium‐Catalyzed Desymmetric Mono‐Hydrogenation of 1,4‐Dienes

The control of site selectivity in asymmetric mono‐hydrogenation of dienes or polyenes remains largely underdeveloped. Herein, we present a highly efficient desymmetrization of 1,4‐dienes via iridium‐catalyzed site‐ and enantioselective hydrogenation. This methodology demonstrates the first iridium‐...

Descripción completa

Detalles Bibliográficos
Autores principales: Wu, Haibo, Su, Hao, Schulze, Erik J., Peters, Bram B. C., Nolan, Mark D., Yang, Jianping, Singh, Thishana, Ahlquist, Mårten S. G., Andersson, Pher G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456900/
https://www.ncbi.nlm.nih.gov/pubmed/34137493
http://dx.doi.org/10.1002/anie.202107267