Versatile Reaction Pathways of 1,1,3,3,3‐Pentafluoropropene at Rh(I) Complexes [Rh(E)(PEt(3))(3)] (E=H, GePh(3), Si(OEt)(3), F, Cl): C‐F versus C‐H Bond Activation Steps

The reaction of the rhodium(I) complexes [Rh(E)(PEt(3))(3)] (E=GePh(3) (1), H (6), F (7)) with 1,1,3,3,3‐pentafluoropropene afforded the defluorinative germylation products Z/E‐2‐(triphenylgermyl)‐1,3,3,3‐tetrafluoropropene and the fluorido complex [Rh(F)(CF(3)CHCF(2))(PEt(3))(2)] (2) together with...

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Detalles Bibliográficos
Autores principales: Talavera, Maria, Braun, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456946/
https://www.ncbi.nlm.nih.gov/pubmed/34118095
http://dx.doi.org/10.1002/chem.202101508

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456946/
https://www.ncbi.nlm.nih.gov/pubmed/34118095
http://dx.doi.org/10.1002/chem.202101508

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