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Symmetry Breaking and Autocatalytic Amplification in Soai Reaction Confined within UiO‐MOFs under Heterogenous Conditions.

Symmetry breaking is observed in the Soai reaction in a confinement environment provided by zirconium‐based UiO‐MOFs used as crystalline sponges. Subsequent reaction of encapsulated Soai aldehyde with Zn(i‐Pr)(2) vapour promoted absolute asymmetric synthesis of the corresponding alkanol. ATR‐IR and...

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Detalles Bibliográficos
Autores principales:	Rotunno, Giuseppe, Kaur, Gurpreet, Lazzarini, Andrea, Buono, Carlo, Amedjkouh, Mohamed
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456963/ https://www.ncbi.nlm.nih.gov/pubmed/34250741 http://dx.doi.org/10.1002/asia.202100419

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