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Redox‐Switchable Cycloisomerization of Alkynoic Acids with Napthalenediimide‐Derived N‐Heterocyclic Carbene Complexes

Two naphthalene‐diimide (NDI) bis‐imidazolium salts have been used as N‐heterocyclic carbene (NHC) precursors for the preparation of NDI‐functionalized complexes of rhodium and iridium of general formula [MCl(NDI‐NHC)(COD)] (M=Rh, Ir; NDI‐NHC=NDI‐functionalized NHC ligand). Comparison of the IR spec...

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Detalles Bibliográficos
Autores principales: Ruiz‐Zambrana, César, Gutiérrez‐Blanco, Ana, Gonell, Sergio, Poyatos, Macarena, Peris, Eduardo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8457061/
https://www.ncbi.nlm.nih.gov/pubmed/34255909
http://dx.doi.org/10.1002/anie.202107973

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