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Triazine-Based Conjugated Microporous Polymers for Efficient Hydrogen Production
[Image: see text] Developing visible-light-active porous organic polymers with high photocatalytic efficiency is highly desirable. Here, two triazine-based conjugated microporous polymers were synthesized. The structures were controllably adjusted to explore the structure–photocatalytic activity rel...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8459349/ https://www.ncbi.nlm.nih.gov/pubmed/34568658 http://dx.doi.org/10.1021/acsomega.1c02592 |
| Sumario: | [Image: see text] Developing visible-light-active porous organic polymers with high photocatalytic efficiency is highly desirable. Here, two triazine-based conjugated microporous polymers were synthesized. The structures were controllably adjusted to explore the structure–photocatalytic activity relationship. T-CMP-1 containing more triazine units exhibited a hydrogen evolution rate of 3214.3 μmol h(–1) g(–1), much higher than that of T-CMP-2 (242.1 μmol h(–1) g(–1)). The increasing contents of triazine units bring better hydrogen evolution efficiency. |
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