Triazine-Based Conjugated Microporous Polymers for Efficient Hydrogen Production

[Image: see text] Developing visible-light-active porous organic polymers with high photocatalytic efficiency is highly desirable. Here, two triazine-based conjugated microporous polymers were synthesized. The structures were controllably adjusted to explore the structure–photocatalytic activity rel...

Descripción completa

Detalles Bibliográficos
Autores principales: Hao, Wenbo, Chen, Renzeng, Zhang, Yue, Wang, Yuancheng, Zhao, Yingjie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8459349/
https://www.ncbi.nlm.nih.gov/pubmed/34568658
http://dx.doi.org/10.1021/acsomega.1c02592
_version_ 1784571501988544512
author Hao, Wenbo
Chen, Renzeng
Zhang, Yue
Wang, Yuancheng
Zhao, Yingjie
author_facet Hao, Wenbo
Chen, Renzeng
Zhang, Yue
Wang, Yuancheng
Zhao, Yingjie
author_sort Hao, Wenbo
collection PubMed
description [Image: see text] Developing visible-light-active porous organic polymers with high photocatalytic efficiency is highly desirable. Here, two triazine-based conjugated microporous polymers were synthesized. The structures were controllably adjusted to explore the structure–photocatalytic activity relationship. T-CMP-1 containing more triazine units exhibited a hydrogen evolution rate of 3214.3 μmol h(–1) g(–1), much higher than that of T-CMP-2 (242.1 μmol h(–1) g(–1)). The increasing contents of triazine units bring better hydrogen evolution efficiency.
format Online
Article
Text
id pubmed-8459349
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher American Chemical Society
record_format MEDLINE/PubMed
spelling pubmed-84593492021-09-24 Triazine-Based Conjugated Microporous Polymers for Efficient Hydrogen Production Hao, Wenbo Chen, Renzeng Zhang, Yue Wang, Yuancheng Zhao, Yingjie ACS Omega [Image: see text] Developing visible-light-active porous organic polymers with high photocatalytic efficiency is highly desirable. Here, two triazine-based conjugated microporous polymers were synthesized. The structures were controllably adjusted to explore the structure–photocatalytic activity relationship. T-CMP-1 containing more triazine units exhibited a hydrogen evolution rate of 3214.3 μmol h(–1) g(–1), much higher than that of T-CMP-2 (242.1 μmol h(–1) g(–1)). The increasing contents of triazine units bring better hydrogen evolution efficiency. American Chemical Society 2021-09-08 /pmc/articles/PMC8459349/ /pubmed/34568658 http://dx.doi.org/10.1021/acsomega.1c02592 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Hao, Wenbo
Chen, Renzeng
Zhang, Yue
Wang, Yuancheng
Zhao, Yingjie
Triazine-Based Conjugated Microporous Polymers for Efficient Hydrogen Production
title Triazine-Based Conjugated Microporous Polymers for Efficient Hydrogen Production
title_full Triazine-Based Conjugated Microporous Polymers for Efficient Hydrogen Production
title_fullStr Triazine-Based Conjugated Microporous Polymers for Efficient Hydrogen Production
title_full_unstemmed Triazine-Based Conjugated Microporous Polymers for Efficient Hydrogen Production
title_short Triazine-Based Conjugated Microporous Polymers for Efficient Hydrogen Production
title_sort triazine-based conjugated microporous polymers for efficient hydrogen production
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8459349/
https://www.ncbi.nlm.nih.gov/pubmed/34568658
http://dx.doi.org/10.1021/acsomega.1c02592
work_keys_str_mv AT haowenbo triazinebasedconjugatedmicroporouspolymersforefficienthydrogenproduction
AT chenrenzeng triazinebasedconjugatedmicroporouspolymersforefficienthydrogenproduction
AT zhangyue triazinebasedconjugatedmicroporouspolymersforefficienthydrogenproduction
AT wangyuancheng triazinebasedconjugatedmicroporouspolymersforefficienthydrogenproduction
AT zhaoyingjie triazinebasedconjugatedmicroporouspolymersforefficienthydrogenproduction

Ejemplares similares