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Influence of Temperature on ZnO/Co(3)O(4) Nanocomposites for High Energy Storage Supercapacitors

[Image: see text] We developed a two-step chemical bath deposition method followed by calcination for the production of ZnO/Co(3)O(4) nanocomposites. In aqueous reactions, ZnO nanotubes were first densely grown on Ni foam, and then flat nanosheets of Co(3)O(4) developed and formed a porous film. The...

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Detalles Bibliográficos
Autores principales: Abebe, Eshetu M., Ujihara, Masaki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8459362/
https://www.ncbi.nlm.nih.gov/pubmed/34568655
http://dx.doi.org/10.1021/acsomega.1c02059
Descripción
Sumario:[Image: see text] We developed a two-step chemical bath deposition method followed by calcination for the production of ZnO/Co(3)O(4) nanocomposites. In aqueous reactions, ZnO nanotubes were first densely grown on Ni foam, and then flat nanosheets of Co(3)O(4) developed and formed a porous film. The aspect ratio and conductivity of the Co(3)O(4) nanosheets were improved by the existence of the ZnO nanotubes, while the bath deposition from a mixture of Zn/Co precursors (one-step method) resulted in a wrinkled plate of Zn/Co oxides. As a supercapacitor electrode, the ZnO/Co(3)O(4) nanosheets formed by the two-step method exhibited a high capacitance, and after being calcined at 450 °C, these nanosheets attained the highest specific capacitance (940 F g(–1)) at a scan rate of 5 mV s(–1) in the cyclic voltammetry analysis. This value was significantly higher than those of single-component electrodes, Co(3)O(4) (785 F g(–1)) and ZnO (200 F g(–1)); therefore, the presence of a synergistic effect was suggested. From the charge/discharge curves, the specific capacitance of ZnO/Co(3)O(4) calcined at 450 °C was calculated to be 740 F g(–1) at a current density of 0.75 A g(–1), and 85.7% of the initial capacitance was retained after 1000 cycles. A symmetrical configuration exhibited a good cycling stability (Coulombic efficiency of 99.6% over 1000 cycles) and satisfied both the energy density (36.6 Wh kg(–1)) and the power density (356 W kg(–1)). Thus, the ZnO/Co(3)O(4) nanocomposite prepared by this simple two-step chemical bath deposition and subsequent calcination at 450 °C is a promising material for pseudocapacitors. Furthermore, this approach can be applied to other metal oxide nanocomposites with intricate structures to extend the design possibility of active materials for electrochemical devices.