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Synthesis of novel hexamolybdenum cluster-functionalized copper hydroxide nanocomposites and its catalytic activity for organic molecule degradation
A novel heterogeneous catalytic nanomaterial based on a molybdenum cluster-based halide (MC) and a single-layered copper hydroxynitrate (CHN) was first prepared by colloidal processing under ambient conditions. The results of the elemental composition and crystalline pattern indicated that CHN was c...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Taylor & Francis
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8463035/ https://www.ncbi.nlm.nih.gov/pubmed/34566493 http://dx.doi.org/10.1080/14686996.2021.1961559 |
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author | Nguyen, Thi Kim Ngan Bourgès, Cédric Naka, Takashi Grasset, Fabien Dumait, Noée Cordier, Stéphane Mori, Takao Ohashi, Naoki Uchikoshi, Tetsuo |
author_facet | Nguyen, Thi Kim Ngan Bourgès, Cédric Naka, Takashi Grasset, Fabien Dumait, Noée Cordier, Stéphane Mori, Takao Ohashi, Naoki Uchikoshi, Tetsuo |
author_sort | Nguyen, Thi Kim Ngan |
collection | PubMed |
description | A novel heterogeneous catalytic nanomaterial based on a molybdenum cluster-based halide (MC) and a single-layered copper hydroxynitrate (CHN) was first prepared by colloidal processing under ambient conditions. The results of the elemental composition and crystalline pattern indicated that CHN was comprehensively synthesized with the support of the MC compound. The absorbing characteristic in the ultraviolet and near-infrared regions was promoted by both of the ingredients. The proper chemical interaction between the materials is a crucial reason to modify the structure of the MCs and only a small decrease in the magnetic susceptibility of CHN. The heterogeneous catalytic activity of the obtained MC@CHN material was found to have a high efficiency and excellent reuse when it is activated by hydrogen peroxide (H(2)O(2)) for the degrading reaction of the organic pollutant at room temperature. A reasonable catalytic mechanism was proposed to explain the distinct role of the copper compound, Mo(6) compound, and H(2)O(2) in the production of the radical hydroxyl ion. This novel nanomaterial will be an environmentally promising candidate for dye removal. |
format | Online Article Text |
id | pubmed-8463035 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | Taylor & Francis |
record_format | MEDLINE/PubMed |
spelling | pubmed-84630352021-09-25 Synthesis of novel hexamolybdenum cluster-functionalized copper hydroxide nanocomposites and its catalytic activity for organic molecule degradation Nguyen, Thi Kim Ngan Bourgès, Cédric Naka, Takashi Grasset, Fabien Dumait, Noée Cordier, Stéphane Mori, Takao Ohashi, Naoki Uchikoshi, Tetsuo Sci Technol Adv Mater Engineering and Structural materials A novel heterogeneous catalytic nanomaterial based on a molybdenum cluster-based halide (MC) and a single-layered copper hydroxynitrate (CHN) was first prepared by colloidal processing under ambient conditions. The results of the elemental composition and crystalline pattern indicated that CHN was comprehensively synthesized with the support of the MC compound. The absorbing characteristic in the ultraviolet and near-infrared regions was promoted by both of the ingredients. The proper chemical interaction between the materials is a crucial reason to modify the structure of the MCs and only a small decrease in the magnetic susceptibility of CHN. The heterogeneous catalytic activity of the obtained MC@CHN material was found to have a high efficiency and excellent reuse when it is activated by hydrogen peroxide (H(2)O(2)) for the degrading reaction of the organic pollutant at room temperature. A reasonable catalytic mechanism was proposed to explain the distinct role of the copper compound, Mo(6) compound, and H(2)O(2) in the production of the radical hydroxyl ion. This novel nanomaterial will be an environmentally promising candidate for dye removal. Taylor & Francis 2021-09-15 /pmc/articles/PMC8463035/ /pubmed/34566493 http://dx.doi.org/10.1080/14686996.2021.1961559 Text en © 2021 The Author(s). Published by National Institute for Materials Science in partnership with Taylor & Francis Group. https://creativecommons.org/licenses/by/4.0/This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) ), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. |
spellingShingle | Engineering and Structural materials Nguyen, Thi Kim Ngan Bourgès, Cédric Naka, Takashi Grasset, Fabien Dumait, Noée Cordier, Stéphane Mori, Takao Ohashi, Naoki Uchikoshi, Tetsuo Synthesis of novel hexamolybdenum cluster-functionalized copper hydroxide nanocomposites and its catalytic activity for organic molecule degradation |
title | Synthesis of novel hexamolybdenum cluster-functionalized copper hydroxide nanocomposites and its catalytic activity for organic molecule degradation |
title_full | Synthesis of novel hexamolybdenum cluster-functionalized copper hydroxide nanocomposites and its catalytic activity for organic molecule degradation |
title_fullStr | Synthesis of novel hexamolybdenum cluster-functionalized copper hydroxide nanocomposites and its catalytic activity for organic molecule degradation |
title_full_unstemmed | Synthesis of novel hexamolybdenum cluster-functionalized copper hydroxide nanocomposites and its catalytic activity for organic molecule degradation |
title_short | Synthesis of novel hexamolybdenum cluster-functionalized copper hydroxide nanocomposites and its catalytic activity for organic molecule degradation |
title_sort | synthesis of novel hexamolybdenum cluster-functionalized copper hydroxide nanocomposites and its catalytic activity for organic molecule degradation |
topic | Engineering and Structural materials |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8463035/ https://www.ncbi.nlm.nih.gov/pubmed/34566493 http://dx.doi.org/10.1080/14686996.2021.1961559 |
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