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Adsorption Performance of Amino Functionalized Magnetic Molecular Sieve Adsorbent for Effective Removal of Lead Ion from Aqueous Solution
Lead ion (Pb(2+)) has high toxicity and brings great harm to human body. It is very important to find an effective method to address lead ion pollution. In this work, amino functionalized CoFe(2)O(4)/SBA–15 nanocomposite (NH(2)–CoFe(2)O(4)/SBA–15) was prepared for the effective removal of Pb(2+) fro...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8467783/ https://www.ncbi.nlm.nih.gov/pubmed/34578672 http://dx.doi.org/10.3390/nano11092353 |
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author | Guo, Chuanen Wang, Yingying Wang, Fangzheng Wang, Yaoguang |
author_facet | Guo, Chuanen Wang, Yingying Wang, Fangzheng Wang, Yaoguang |
author_sort | Guo, Chuanen |
collection | PubMed |
description | Lead ion (Pb(2+)) has high toxicity and brings great harm to human body. It is very important to find an effective method to address lead ion pollution. In this work, amino functionalized CoFe(2)O(4)/SBA–15 nanocomposite (NH(2)–CoFe(2)O(4)/SBA–15) was prepared for the effective removal of Pb(2+) from aqueous solution. The prepared NH(2)–CoFe(2)O(4)/SBA–15 adsorbent was manifested by using scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), Fourier transform infrared spectrum (FTIR), X-ray powder diffraction (XRD), and Brunauer-Emmett-Teller (BET) analysis. In the meantime, the adsorption conditions, including pH, adsorbent dosage, and adsorption time, were studied. The investigation of adsorption kinetics revealed that the adsorption results conform to the pseudo-first-order kinetic model. The adsorption isotherms research displayed that the adsorption was consistent with the Freundlich model, demonstrating that the adsorption for Pb(2+) with the prepared adsorbent was a multimolecular layer adsorption process. In addition, the thermodynamic investigations (ΔG < 0, ΔH > 0, ΔS > 0) demonstrated that the adsorption for Pb(2+) with the prepared adsorbent was endothermic and spontaneous. Moreover, the prepared adsorbent showed superior anti-interference performance and reusability, implying the potential application of the adsorbent in actual water treatment. Furthermore, this research may provide a reference and basis for the study of other heavy metal ions. |
format | Online Article Text |
id | pubmed-8467783 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-84677832021-09-27 Adsorption Performance of Amino Functionalized Magnetic Molecular Sieve Adsorbent for Effective Removal of Lead Ion from Aqueous Solution Guo, Chuanen Wang, Yingying Wang, Fangzheng Wang, Yaoguang Nanomaterials (Basel) Article Lead ion (Pb(2+)) has high toxicity and brings great harm to human body. It is very important to find an effective method to address lead ion pollution. In this work, amino functionalized CoFe(2)O(4)/SBA–15 nanocomposite (NH(2)–CoFe(2)O(4)/SBA–15) was prepared for the effective removal of Pb(2+) from aqueous solution. The prepared NH(2)–CoFe(2)O(4)/SBA–15 adsorbent was manifested by using scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), Fourier transform infrared spectrum (FTIR), X-ray powder diffraction (XRD), and Brunauer-Emmett-Teller (BET) analysis. In the meantime, the adsorption conditions, including pH, adsorbent dosage, and adsorption time, were studied. The investigation of adsorption kinetics revealed that the adsorption results conform to the pseudo-first-order kinetic model. The adsorption isotherms research displayed that the adsorption was consistent with the Freundlich model, demonstrating that the adsorption for Pb(2+) with the prepared adsorbent was a multimolecular layer adsorption process. In addition, the thermodynamic investigations (ΔG < 0, ΔH > 0, ΔS > 0) demonstrated that the adsorption for Pb(2+) with the prepared adsorbent was endothermic and spontaneous. Moreover, the prepared adsorbent showed superior anti-interference performance and reusability, implying the potential application of the adsorbent in actual water treatment. Furthermore, this research may provide a reference and basis for the study of other heavy metal ions. MDPI 2021-09-11 /pmc/articles/PMC8467783/ /pubmed/34578672 http://dx.doi.org/10.3390/nano11092353 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Guo, Chuanen Wang, Yingying Wang, Fangzheng Wang, Yaoguang Adsorption Performance of Amino Functionalized Magnetic Molecular Sieve Adsorbent for Effective Removal of Lead Ion from Aqueous Solution |
title | Adsorption Performance of Amino Functionalized Magnetic Molecular Sieve Adsorbent for Effective Removal of Lead Ion from Aqueous Solution |
title_full | Adsorption Performance of Amino Functionalized Magnetic Molecular Sieve Adsorbent for Effective Removal of Lead Ion from Aqueous Solution |
title_fullStr | Adsorption Performance of Amino Functionalized Magnetic Molecular Sieve Adsorbent for Effective Removal of Lead Ion from Aqueous Solution |
title_full_unstemmed | Adsorption Performance of Amino Functionalized Magnetic Molecular Sieve Adsorbent for Effective Removal of Lead Ion from Aqueous Solution |
title_short | Adsorption Performance of Amino Functionalized Magnetic Molecular Sieve Adsorbent for Effective Removal of Lead Ion from Aqueous Solution |
title_sort | adsorption performance of amino functionalized magnetic molecular sieve adsorbent for effective removal of lead ion from aqueous solution |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8467783/ https://www.ncbi.nlm.nih.gov/pubmed/34578672 http://dx.doi.org/10.3390/nano11092353 |
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