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Two-Dimensional Perovskite Crystals Formed by Atomic Layer Deposition of CaTiO(3) on γ-Al(2)O(3)

CaTiO(3) films with an average thickness of 0.5 nm were deposited onto γ-Al(2)O(3) by Atomic Layer Deposition (ALD) and then characterized by a range of techniques, including X-ray Diffraction (XRD) and High-Resolution, Transmission Electron Microscopy (HRTEM). The results demonstrate that the films...

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Autores principales: Cao, Tianyu, Kwon, Ohhun, Lin, Chao, Vohs, John M., Gorte, Raymond J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8469333/
https://www.ncbi.nlm.nih.gov/pubmed/34578523
http://dx.doi.org/10.3390/nano11092207
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author Cao, Tianyu
Kwon, Ohhun
Lin, Chao
Vohs, John M.
Gorte, Raymond J.
author_facet Cao, Tianyu
Kwon, Ohhun
Lin, Chao
Vohs, John M.
Gorte, Raymond J.
author_sort Cao, Tianyu
collection PubMed
description CaTiO(3) films with an average thickness of 0.5 nm were deposited onto γ-Al(2)O(3) by Atomic Layer Deposition (ALD) and then characterized by a range of techniques, including X-ray Diffraction (XRD) and High-Resolution, Transmission Electron Microscopy (HRTEM). The results demonstrate that the films form two-dimensional crystallites over the entire surface. Lattice fringes from HRTEM indicate that the crystallites range in size from 5 to 20 nm and are oriented in various directions. Films of the same thickness on SiO(2) remained amorphous, indicating that the support played a role in forming the crystallites.
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spelling pubmed-84693332021-09-27 Two-Dimensional Perovskite Crystals Formed by Atomic Layer Deposition of CaTiO(3) on γ-Al(2)O(3) Cao, Tianyu Kwon, Ohhun Lin, Chao Vohs, John M. Gorte, Raymond J. Nanomaterials (Basel) Article CaTiO(3) films with an average thickness of 0.5 nm were deposited onto γ-Al(2)O(3) by Atomic Layer Deposition (ALD) and then characterized by a range of techniques, including X-ray Diffraction (XRD) and High-Resolution, Transmission Electron Microscopy (HRTEM). The results demonstrate that the films form two-dimensional crystallites over the entire surface. Lattice fringes from HRTEM indicate that the crystallites range in size from 5 to 20 nm and are oriented in various directions. Films of the same thickness on SiO(2) remained amorphous, indicating that the support played a role in forming the crystallites. MDPI 2021-08-27 /pmc/articles/PMC8469333/ /pubmed/34578523 http://dx.doi.org/10.3390/nano11092207 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Cao, Tianyu
Kwon, Ohhun
Lin, Chao
Vohs, John M.
Gorte, Raymond J.
Two-Dimensional Perovskite Crystals Formed by Atomic Layer Deposition of CaTiO(3) on γ-Al(2)O(3)
title Two-Dimensional Perovskite Crystals Formed by Atomic Layer Deposition of CaTiO(3) on γ-Al(2)O(3)
title_full Two-Dimensional Perovskite Crystals Formed by Atomic Layer Deposition of CaTiO(3) on γ-Al(2)O(3)
title_fullStr Two-Dimensional Perovskite Crystals Formed by Atomic Layer Deposition of CaTiO(3) on γ-Al(2)O(3)
title_full_unstemmed Two-Dimensional Perovskite Crystals Formed by Atomic Layer Deposition of CaTiO(3) on γ-Al(2)O(3)
title_short Two-Dimensional Perovskite Crystals Formed by Atomic Layer Deposition of CaTiO(3) on γ-Al(2)O(3)
title_sort two-dimensional perovskite crystals formed by atomic layer deposition of catio(3) on γ-al(2)o(3)
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8469333/
https://www.ncbi.nlm.nih.gov/pubmed/34578523
http://dx.doi.org/10.3390/nano11092207
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