Eight-Fold Interpenetrating Diamondoid Coordination Polymers for Sensing Volatile Organic Compounds and Metal Ions

Reactions of divalent metal salts with 4,4-oxybis(N-(pyridine-4-yl)-benzamide), L, and naphthalene-1,4-dicarboxylic acid (1,4-H(2)NDC) in various solvents gave [Zn(L)(1,4-NDC)·H(2)O](n), 1, [Cd(L)(1,4-NDC)(H(2)O)·MeOH](n), 2, and [Co(L)(1,4-NDC)(H(2)O)(0.5)·MeOH](n), 3, which have been structurally...

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Autores principales: Lakshmanan, Venkatesan, Lai, Yi-Ting, Yang, Xiang-Kai, Govindaraj, Manivannan, Lin, Chia-Her, Chen, Jhy-Der
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8470056/
https://www.ncbi.nlm.nih.gov/pubmed/34577919
http://dx.doi.org/10.3390/polym13183018
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author Lakshmanan, Venkatesan
Lai, Yi-Ting
Yang, Xiang-Kai
Govindaraj, Manivannan
Lin, Chia-Her
Chen, Jhy-Der
author_facet Lakshmanan, Venkatesan
Lai, Yi-Ting
Yang, Xiang-Kai
Govindaraj, Manivannan
Lin, Chia-Her
Chen, Jhy-Der
author_sort Lakshmanan, Venkatesan
collection PubMed
description Reactions of divalent metal salts with 4,4-oxybis(N-(pyridine-4-yl)-benzamide), L, and naphthalene-1,4-dicarboxylic acid (1,4-H(2)NDC) in various solvents gave [Zn(L)(1,4-NDC)·H(2)O](n), 1, [Cd(L)(1,4-NDC)(H(2)O)·MeOH](n), 2, and [Co(L)(1,4-NDC)(H(2)O)(0.5)·MeOH](n), 3, which have been structurally characterized. Complexes 1–3 show eight-fold interpenetrating frameworks with the dia topology, which exhibit porosities substantiated by CO(2) adsorption, whereas 1 and 2 manifest stability in aqueous environments and show high selectivity toward sensing of mesitylene molecules and Fe(3+) ions with low detection limits and good reusability up to five cycles.
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spelling pubmed-84700562021-09-27 Eight-Fold Interpenetrating Diamondoid Coordination Polymers for Sensing Volatile Organic Compounds and Metal Ions Lakshmanan, Venkatesan Lai, Yi-Ting Yang, Xiang-Kai Govindaraj, Manivannan Lin, Chia-Her Chen, Jhy-Der Polymers (Basel) Article Reactions of divalent metal salts with 4,4-oxybis(N-(pyridine-4-yl)-benzamide), L, and naphthalene-1,4-dicarboxylic acid (1,4-H(2)NDC) in various solvents gave [Zn(L)(1,4-NDC)·H(2)O](n), 1, [Cd(L)(1,4-NDC)(H(2)O)·MeOH](n), 2, and [Co(L)(1,4-NDC)(H(2)O)(0.5)·MeOH](n), 3, which have been structurally characterized. Complexes 1–3 show eight-fold interpenetrating frameworks with the dia topology, which exhibit porosities substantiated by CO(2) adsorption, whereas 1 and 2 manifest stability in aqueous environments and show high selectivity toward sensing of mesitylene molecules and Fe(3+) ions with low detection limits and good reusability up to five cycles. MDPI 2021-09-07 /pmc/articles/PMC8470056/ /pubmed/34577919 http://dx.doi.org/10.3390/polym13183018 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Lakshmanan, Venkatesan
Lai, Yi-Ting
Yang, Xiang-Kai
Govindaraj, Manivannan
Lin, Chia-Her
Chen, Jhy-Der
Eight-Fold Interpenetrating Diamondoid Coordination Polymers for Sensing Volatile Organic Compounds and Metal Ions
title Eight-Fold Interpenetrating Diamondoid Coordination Polymers for Sensing Volatile Organic Compounds and Metal Ions
title_full Eight-Fold Interpenetrating Diamondoid Coordination Polymers for Sensing Volatile Organic Compounds and Metal Ions
title_fullStr Eight-Fold Interpenetrating Diamondoid Coordination Polymers for Sensing Volatile Organic Compounds and Metal Ions
title_full_unstemmed Eight-Fold Interpenetrating Diamondoid Coordination Polymers for Sensing Volatile Organic Compounds and Metal Ions
title_short Eight-Fold Interpenetrating Diamondoid Coordination Polymers for Sensing Volatile Organic Compounds and Metal Ions
title_sort eight-fold interpenetrating diamondoid coordination polymers for sensing volatile organic compounds and metal ions
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8470056/
https://www.ncbi.nlm.nih.gov/pubmed/34577919
http://dx.doi.org/10.3390/polym13183018
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