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Effect of the Epoxide Contents of Liquid Isoprene Rubber as a Processing Aid on the Properties of Silica-Filled Natural Rubber Compounds

In this study, we examined the feasibility of using epoxidized liquid isoprene rubber (E-LqIR) as a processing aid for truck and bus radial (TBR) tire treads and investigated the effects of the epoxide content on the wear resistance, fuel efficiency, and resistance to extraction of the E-LqIRs. The...

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Autores principales: Ryu, Gyeongchan, Kim, Donghyuk, Song, Sanghoon, Hwang, Kiwon, Kim, Wonho
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8472425/
https://www.ncbi.nlm.nih.gov/pubmed/34577927
http://dx.doi.org/10.3390/polym13183026
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author Ryu, Gyeongchan
Kim, Donghyuk
Song, Sanghoon
Hwang, Kiwon
Kim, Wonho
author_facet Ryu, Gyeongchan
Kim, Donghyuk
Song, Sanghoon
Hwang, Kiwon
Kim, Wonho
author_sort Ryu, Gyeongchan
collection PubMed
description In this study, we examined the feasibility of using epoxidized liquid isoprene rubber (E-LqIR) as a processing aid for truck and bus radial (TBR) tire treads and investigated the effects of the epoxide content on the wear resistance, fuel efficiency, and resistance to extraction of the E-LqIRs. The results confirmed that, compared to the treated distillate aromatic extract (TDAE) oil, the E-LqIRs could enhance the filler–rubber interactions and reduce the oil migration. However, the consumption of sulfur by the E-LqIRs resulted in a lower crosslink density compared to that of the TDAE oil, and the higher epoxide content decreased the wear resistance and fuel efficiency because of the increased glass-transition temperature (T(g)). In contrast, the E-LqIR with a low epoxide content of 6 mol% had no significant effect on the T(g) of the final compound and resulted in superior wear resistance and fuel efficiency, compared to those shown by TDAE oil, because of the higher filler–rubber interactions.
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spelling pubmed-84724252021-09-28 Effect of the Epoxide Contents of Liquid Isoprene Rubber as a Processing Aid on the Properties of Silica-Filled Natural Rubber Compounds Ryu, Gyeongchan Kim, Donghyuk Song, Sanghoon Hwang, Kiwon Kim, Wonho Polymers (Basel) Article In this study, we examined the feasibility of using epoxidized liquid isoprene rubber (E-LqIR) as a processing aid for truck and bus radial (TBR) tire treads and investigated the effects of the epoxide content on the wear resistance, fuel efficiency, and resistance to extraction of the E-LqIRs. The results confirmed that, compared to the treated distillate aromatic extract (TDAE) oil, the E-LqIRs could enhance the filler–rubber interactions and reduce the oil migration. However, the consumption of sulfur by the E-LqIRs resulted in a lower crosslink density compared to that of the TDAE oil, and the higher epoxide content decreased the wear resistance and fuel efficiency because of the increased glass-transition temperature (T(g)). In contrast, the E-LqIR with a low epoxide content of 6 mol% had no significant effect on the T(g) of the final compound and resulted in superior wear resistance and fuel efficiency, compared to those shown by TDAE oil, because of the higher filler–rubber interactions. MDPI 2021-09-07 /pmc/articles/PMC8472425/ /pubmed/34577927 http://dx.doi.org/10.3390/polym13183026 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Ryu, Gyeongchan
Kim, Donghyuk
Song, Sanghoon
Hwang, Kiwon
Kim, Wonho
Effect of the Epoxide Contents of Liquid Isoprene Rubber as a Processing Aid on the Properties of Silica-Filled Natural Rubber Compounds
title Effect of the Epoxide Contents of Liquid Isoprene Rubber as a Processing Aid on the Properties of Silica-Filled Natural Rubber Compounds
title_full Effect of the Epoxide Contents of Liquid Isoprene Rubber as a Processing Aid on the Properties of Silica-Filled Natural Rubber Compounds
title_fullStr Effect of the Epoxide Contents of Liquid Isoprene Rubber as a Processing Aid on the Properties of Silica-Filled Natural Rubber Compounds
title_full_unstemmed Effect of the Epoxide Contents of Liquid Isoprene Rubber as a Processing Aid on the Properties of Silica-Filled Natural Rubber Compounds
title_short Effect of the Epoxide Contents of Liquid Isoprene Rubber as a Processing Aid on the Properties of Silica-Filled Natural Rubber Compounds
title_sort effect of the epoxide contents of liquid isoprene rubber as a processing aid on the properties of silica-filled natural rubber compounds
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8472425/
https://www.ncbi.nlm.nih.gov/pubmed/34577927
http://dx.doi.org/10.3390/polym13183026
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