Synthesis and investigation on optical and electrochemical properties of 2,4-diaryl-9-chloro-5,6,7,8-tetrahydroacridines

A facile synthesis of 2,4-diaryl-9-chloro-5,6,7,8-tetrahydroacridine derivatives is reported which is based on POCl(3)-mediated cyclodehydration followed by double Suzuki–Miyaura cross-coupling. The absorption and fluorescence properties of the obtained products were investigated and their HOMO/LUMO...

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Autores principales: Tka, Najeh, Ayed, Mohamed Adnene Hadj, Braiek, Mourad Ben, Jabli, Mahjoub, Langer, Peter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2021
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8474071/
https://www.ncbi.nlm.nih.gov/pubmed/34630725
http://dx.doi.org/10.3762/bjoc.17.162
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author Tka, Najeh
Ayed, Mohamed Adnene Hadj
Braiek, Mourad Ben
Jabli, Mahjoub
Langer, Peter
author_facet Tka, Najeh
Ayed, Mohamed Adnene Hadj
Braiek, Mourad Ben
Jabli, Mahjoub
Langer, Peter
author_sort Tka, Najeh
collection PubMed
description A facile synthesis of 2,4-diaryl-9-chloro-5,6,7,8-tetrahydroacridine derivatives is reported which is based on POCl(3)-mediated cyclodehydration followed by double Suzuki–Miyaura cross-coupling. The absorption and fluorescence properties of the obtained products were investigated and their HOMO/LUMO energy levels were estimated by cyclic voltammetry measurements. Besides, density functional theory calculations were carried out for further exploration of their electronic properties.
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spelling pubmed-84740712021-10-07 Synthesis and investigation on optical and electrochemical properties of 2,4-diaryl-9-chloro-5,6,7,8-tetrahydroacridines Tka, Najeh Ayed, Mohamed Adnene Hadj Braiek, Mourad Ben Jabli, Mahjoub Langer, Peter Beilstein J Org Chem Full Research Paper A facile synthesis of 2,4-diaryl-9-chloro-5,6,7,8-tetrahydroacridine derivatives is reported which is based on POCl(3)-mediated cyclodehydration followed by double Suzuki–Miyaura cross-coupling. The absorption and fluorescence properties of the obtained products were investigated and their HOMO/LUMO energy levels were estimated by cyclic voltammetry measurements. Besides, density functional theory calculations were carried out for further exploration of their electronic properties. Beilstein-Institut 2021-09-20 /pmc/articles/PMC8474071/ /pubmed/34630725 http://dx.doi.org/10.3762/bjoc.17.162 Text en Copyright © 2021, Tka et al. https://creativecommons.org/licenses/by/4.0/https://www.beilstein-journals.org/bjoc/terms/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0 (https://creativecommons.org/licenses/by/4.0/) ). Please note that the reuse, redistribution and reproduction in particular requires that the author(s) and source are credited and that individual graphics may be subject to special legal provisions. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms/terms)
spellingShingle Full Research Paper
Tka, Najeh
Ayed, Mohamed Adnene Hadj
Braiek, Mourad Ben
Jabli, Mahjoub
Langer, Peter
Synthesis and investigation on optical and electrochemical properties of 2,4-diaryl-9-chloro-5,6,7,8-tetrahydroacridines
title Synthesis and investigation on optical and electrochemical properties of 2,4-diaryl-9-chloro-5,6,7,8-tetrahydroacridines
title_full Synthesis and investigation on optical and electrochemical properties of 2,4-diaryl-9-chloro-5,6,7,8-tetrahydroacridines
title_fullStr Synthesis and investigation on optical and electrochemical properties of 2,4-diaryl-9-chloro-5,6,7,8-tetrahydroacridines
title_full_unstemmed Synthesis and investigation on optical and electrochemical properties of 2,4-diaryl-9-chloro-5,6,7,8-tetrahydroacridines
title_short Synthesis and investigation on optical and electrochemical properties of 2,4-diaryl-9-chloro-5,6,7,8-tetrahydroacridines
title_sort synthesis and investigation on optical and electrochemical properties of 2,4-diaryl-9-chloro-5,6,7,8-tetrahydroacridines
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8474071/
https://www.ncbi.nlm.nih.gov/pubmed/34630725
http://dx.doi.org/10.3762/bjoc.17.162
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