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Ultrafast 2D (1)H–(1)H NMR spectroscopy of DNP-hyperpolarised substrates for the analysis of mixtures

We show that TOCSY and multiple-quantum (MQ) 2D NMR spectra can be obtained for mixtures of substrates hyperpolarised by dissolution dynamic nuclear polarisation (D-DNP). This is achieved by combining optimised transfer settings for D-DNP, with ultrafast 2D NMR experiments based on spatiotemporal en...

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Detalles Bibliográficos
Autores principales: Singh, Kawarpal, Jacquemmoz, Corentin, Giraudeau, Patrick, Frydman, Lucio, Dumez, Jean-Nicolas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8477446/
https://www.ncbi.nlm.nih.gov/pubmed/34291258
http://dx.doi.org/10.1039/d1cc03079e